Synthesis of Cyclic β-1,6-Oligosaccharides by Electrochemical Polyglycosylation of glucosamine monomers

Submitting author affiliation:
Tottori University, Tottori city, Japan

Beilstein Arch. 2024, 202423. https://doi.org/10.3762/bxiv.2024.23.v1

Published 16 Apr 2024

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Abstract

Synthesis of protected precursors of cyclic β-1,6-oligoglucosamines by electrochemical polyglycosylation of thioglycosides as a monomer is performed. The monomer with 2,3-oxazolidinone protecting group afforded the cyclic disaccharide exclusively. Cyclic oligosaccharides up to trisaccharide were obtained using the monomer with 2-deoxy-2-azido group.

Keywords: cyclic oligosaccharide; electrochemical glycosylation; glucosamine; polyglycosylation

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Rahman, M. A.; Endo, H.; Yamamoto, T.; Okushiba, S.; Sasaki, N.; Nokami, T. Beilstein Arch. 2024, 202423. doi:10.3762/bxiv.2024.23.v1

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