An exceptional P-H phosphonite: Biphenyl-2,2'-bisfenchylchlorophosphite and derived ligands (BIFOPs) in enantioselective copper-catalyzed 1,4-additions

Scholarly Works

• Brüllingen, E.; Neudörfl, J.-M.; Goldfuss, B. Ligand's electronegativity controls the sense of enantioselectivity in BIFOP-X palladium-catalyzed allylic alkylations. New Journal of Chemistry 2019, 43, 15743–15753. doi:10.1039/c9nj02798j
• Brüllingen, E.; Neudörfl, J.-M.; Goldfuss, B. Enantioselective Cu-catalyzed 1,4-additions of organozinc and Grignard reagents to enones: exceptional performance of the hydrido-phosphite-ligand BIFOP-H. New Journal of Chemistry 2019, 43, 4787–4799. doi:10.1039/c8nj05886e
• Fox, F.; Neudörfl, J. M.; Goldfuss, B. Silanediol versus chlorosilanol: hydrolyses and hydrogen-bonding catalyses with fenchole-based silanes. Beilstein journal of organic chemistry 2019, 15, 167–186. doi:10.3762/bjoc.15.17
• Trillo, R. B.; Neudörfl, J. M.; Goldfuss, B. An unusually stable chlorophosphite: What makes BIFOP-Cl so robust against hydrolysis?. Beilstein journal of organic chemistry 2015, 11, 313–322. doi:10.3762/bjoc.11.36
• Trillo, R. B.; Leven, M.; Neudörfl, J. M.; Goldfuss, B. Electronegativity Governs Enantioselectivity: Alkyl-Aryl Cross-Coupling with Fenchol-Based Palladium-Phosphorus Halide Catalysts. Advanced Synthesis & Catalysis 2012, 354, 1451–1465. doi:10.1002/adsc.201100924
• Lefort and, L.; de Vries, J. G. doi:10.1002/9781118299715.ch4
• Lal, S.; McNally, J.; White, A. J. P.; Díez-González, S. Novel Phosphinite and Phosphonite Copper(I) Complexes: Efficient Catalysts for Click Azide–Alkyne Cycloaddition Reactions. Organometallics 2011, 30, 6225–6232. doi:10.1021/om200791u
• Gliga, A.; Goldfuss, B.; Neudörfl, J. M. Lithium phosphonate umpolung catalysts: Do fluoro substituents increase the catalytic activity?. Beilstein journal of organic chemistry 2011, 7, 1189–1197. doi:10.3762/bjoc.7.138
• Amberg, M.; Kempter, I.; Bergsträßer, U.; Stapf, G.; Hartung, J. Derivatizing agents from phosphorus trichloride and terpenyl tartrates for determining the enantiomeric purity of alcohols. Tetrahedron: Asymmetry 2011, 22, 752–760. doi:10.1016/j.tetasy.2011.04.004
• Hobuß, D.; Baro, A.; Axenov, K. V.; Laschat, S.; Frey, W. P-Stereogenic Pinene-Derived Phosphoramidites and Their Use in Copper-Catalyzed Conjugate Additions†. European Journal of Inorganic Chemistry 2011, 2011, 384–392. doi:10.1002/ejic.201000946
• Gliga, A.; Klare, H.; Schumacher, M.; Soki, F.; Neudörfl, J. M.; Goldfuss, B. New Umpolung Catalysts: Reactivity and Selectivity of Terpenol-Based Lithium Phosphonates in Enantioselective Benzoin-Type Couplings†. European Journal of Organic Chemistry 2010, 2011, 256–263. doi:10.1002/ejoc.201001295
• Alpagut, Y.; Goldfuss, B.; Neudörfl, J.-M. Control of asymmetric biaryl conformations with terpenol moieties: syntheses, structures and energetics of new enantiopure C2-symmetric diols. Beilstein journal of organic chemistry 2008, 4, 25. doi:10.3762/bjoc.4.25
• Betz, R.; Klüfers, P. Hydrido-bis(meso-oxolanylen-3,4-dioxy)-λ5-phosphane. Phosphorus, Sulfur, and Silicon and the Related Elements 2008, 183, 1615–1629. doi:10.1080/10426500701696829
• Soki, F.; Neudörfl, J.-M.; Goldfuss, B. Homo- vs. heterometallic organoaluminum fencholates: Structures and selectivities. Journal of Organometallic Chemistry 2008, 693, 2139–2146. doi:10.1016/j.jorganchem.2008.03.013
• Goldfuss, B. Electronic differentiations in palladium-catalyzed allylic substitutions. Journal of Organometallic Chemistry 2006, 691, 4508–4513. doi:10.1016/j.jorganchem.2006.01.061
• Lange, D.; Neudörfl, J. M.; Goldfuss, B. New chiral lithium aluminum hydrides based on biphenyl-2,2′-bisfenchol (BIFOL): structural analyses and enantioselective reductions of aryl alkyl ketones. Tetrahedron 2006, 62, 3704–3709. doi:10.1016/j.tet.2006.01.060
• Goldfuss, B.; Löschmann, T.; Kop-Weiershausen, T.; Neudörfl, J. M.; Rominger, F. A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts. Beilstein journal of organic chemistry 2006, 2, 7. doi:10.1186/1860-5397-2-7

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