Preparation of phosphines through C–P bond formation

Scholarly Works

• Peng, J.; Wang, A.; Liu, Y.; Chen, F.; Tang, G.; Zhao, Y. Selective Functionalization of White Phosphorus with Alkyl Bromides under Photocatalytic Conditions: A Chlorine-Free Protocol to Dialkyl and Trialkyl Phosphine Oxides. Organic Letters 2024. doi:10.1021/acs.orglett.4c03494
• Zhao, S.; Liu, J.; Xu, X.; Chen, X.; Kato, T.; Wang, Z.; Liu, Y.; Maruoka, K. Enantioselective Synthesis of P-Chiral Phosphine Oxides Bearing an All-Carbon Quaternary Stereogenic Center via Palladium-Catalyzed Domino Heck–Suzuki Reaction. ACS Catalysis 2024, 14, 14762–14768. doi:10.1021/acscatal.4c04958
• Wang, C.; Tang, M.; Wang, Y.; Huang, S.; Xie, L.-G. Photoinduced, Redox-Neutral Decyanative and Defluorinative Phosphination of (Hetero)Arenes. Organic letters 2024, 26, 8154–8158. doi:10.1021/acs.orglett.4c03049
• Rina, Y. A.; Schmidt, J. A. R. Alpha-metalated N,N-dimethylbenzylamine rare-earth metal complexes and their catalytic applications. Dalton transactions (Cambridge, England : 2003) 2024, 53, 13232–13247. doi:10.1039/d4dt00826j
• Saleh, R. A.; Mohamad, H. A.; Ashfaq, M.; Al-Jibori, S. A.; Tahir, M. N. A Slightly Distorted Square Pyramidal Nickel(II) Complex: Synthesis, Characterizations, X-ray Crystal Structure, Anticancer Activity, Electrochemistry, DFT and Hirshfield Surface Studies of [NiCl(dppe)2]Cl.CH2Cl2, dppe: 1,2-Bis(Diphenylphosphino)Ethane. Chemistry Africa 2024. doi:10.1007/s42250-024-01039-5
• Sun, B.-Q.; Yang, J.; Fan, L.; Xu, Q.; Wang, S.; Zhong, H.; Xiang, H.-Y. Base-Promoted Nucleophilic Phosphorylation of Benzyl Fluorides via C(sp3)-F Cleavage. The Journal of organic chemistry 2024, 89, 11739–11746. doi:10.1021/acs.joc.4c00098
• Zhou, H.; Xue, Y.; Zhou, X.; Yao, H.; Lin, A. Palladium-Catalyzed Asymmetric Desymmetrization for the Simultaneous Construction of Chiral Phosphorus and Quaternary Carbon Stereocenters. Organic letters 2024, 26, 5934–5939. doi:10.1021/acs.orglett.4c01863
• Jing, B.; Zhu, C.; Song, H.; Li, J.; Cui, C. Ytterbium(II) Complex-Catalyzed Selective Single and Double Hydrophosphination of 1,3-Enynes. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202401234. doi:10.1002/chem.202401234
• Pedrazzani, R.; Kiriakidi, S.; Monari, M.; Lazzarini, I.; Bertuzzi, G.; López, C. S.; Bandini, M. Fluorinated Biphenyl Phosphine Ligands for Accelerated [Au(I)]-Catalysis. ACS Catalysis 2024, 14, 6128–6136. doi:10.1021/acscatal.4c00593
• Sun, H.; Wang, J.; Du, Z.; Zhang, K.; Hu, J.; Jing, S. Direct Synthesis of Tertiary Phosphines via Alkoxide-Mediated Deborylative Phosphination of Organoboronates. Organic letters 2024, 26, 1618–1622. doi:10.1021/acs.orglett.4c00001
• Chen, Z.-J.; Fan, L.-J.; Xie, P.-P.; Qian, P.-F.; Hu, X.; Zhou, T.; Shi, B.-F. Pd(II)-Catalyzed enantioselective C-H olefination toward the synthesis of P-stereogenic phosphinamides. Chemical communications (Cambridge, England) 2024, 60, 1623–1626. doi:10.1039/d3cc05052a
• Chen, X.; Li, G.; Ma, H.; Zhao, S.-Y.; Liu, W. Deoxygenative 1,3-carbophosphination of allylic alcohols enabled by manganese pincer catalyst. Organic Chemistry Frontiers 2024. doi:10.1039/d4qo01652a
• van der Westhuizen, D.; Castro, A. C.; Hazari, N.; Gevorgyan, A. Bulky, electron-rich, renewable: analogues of Beller's phosphine for cross-couplings. Catalysis science & technology 2023, 13, 6733–6742. doi:10.1039/d3cy01375h
• Tobrman, T. Vinyl Esters and Vinyl Sulfonates as Green Alternatives to Vinyl Bromide for the Synthesis of Monosubstituted Alkenes via Transition-Metal-Catalyzed Reactions. Chemistry 2023, 5, 2288–2321. doi:10.3390/chemistry5040153
• Shi, W.; Zhong, P.-F.; Qi, X.-K.; Yang, C.; Guo, L.; Xia, W. Photoinduced ligand-to-iron charge transfer enabled C(sp3)–H phosphorylation of hydrocarbons. Green Chemistry 2023, 25, 7817–7824. doi:10.1039/d3gc02469e
• Tu, Y.-L.; Zhang, B.-B.; Qiu, B.-S.; Wang, Z.-X.; Chen, X.-Y. Cross-Electrophile C-PIII Coupling of Chlorophosphines with Organic Halides: Photoinduced PIII and Aminoalkyl Radical Generation Enabled by Pnictogen Bonding. Angewandte Chemie (International ed. in English) 2023, 62, e202310764. doi:10.1002/anie.202310764
• Tu, Y.; Zhang, B.; Qiu, B.; Wang, Z.; Chen, X. Cross‐Electrophile C−PIIICoupling of Chlorophosphines with Organic Halides: Photoinduced PIIIand Aminoalkyl Radical Generation Enabled by Pnictogen Bonding. Angewandte Chemie 2023, 135. doi:10.1002/ange.202310764
• Chen, F.; Peng, J.; Ying, Y.; Cao, Y.; Xu, P.; Tang, G.; Zhao, Y. Metal-free visible-light-induced phosphorylation of unactivated alkyl iodides with white phosphorus as the P-atom source. Green Chemistry 2023, 25, 6629–6634. doi:10.1039/d3gc01579c
• Igarashi, T.; Shimazumi, R.; Chatani, N.; Tobisu, M. Nickel-catalyzed direct methylation of arylphosphines via carbon-phosphorus bond cleavage using AlMe3. Chemical communications (Cambridge, England) 2023, 59, 9722–9725. doi:10.1039/d3cc02455e
• Xia, G.-D.; Liu, Z.-K.; Zhao, Y.-L.; Jia, F.-C.; Hu, X.-Q. Radical Phosphorylation of Aliphatic C-H Bonds via Iron Photocatalysis. Organic letters 2023, 25, 5279–5284. doi:10.1021/acs.orglett.3c01824

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