Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts

Jong Yeob Jeon, Seong Chan Eo, Jobi Kodiyan Varghese and Bun Yeoul Lee
Beilstein J. Org. Chem. 2014, 10, 1787–1795. https://doi.org/10.3762/bjoc.10.187

Supporting Information

Supporting Information File 1: 1H NMR spectra, 13C NMR spectra, GPC curves, and the pictures of the isolated polymers in PO/PA alternating polymerizations and PO/CO2/PA terpolymerizations.
Format: PDF Size: 1.1 MB Download

Cite the Following Article

Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts
Jong Yeob Jeon, Seong Chan Eo, Jobi Kodiyan Varghese and Bun Yeoul Lee
Beilstein J. Org. Chem. 2014, 10, 1787–1795. https://doi.org/10.3762/bjoc.10.187

How to Cite

Jeon, J. Y.; Eo, S. C.; Varghese, J. K.; Lee, B. Y. Beilstein J. Org. Chem. 2014, 10, 1787–1795. doi:10.3762/bjoc.10.187

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Ren, B.-H.; Fu, J.-M.; Li, W.-B.; Coates, G. W.; Lu, X.-B. Multicomponent Polymerization of β-Propiolactone, Epoxides, Anhydrides, and CO2: Synthesizing Sustainable Materials with Widely Adjustable Properties. Macromolecules 2024. doi:10.1021/acs.macromol.4c01512
  • Fiorentini, F.; Eisenhardt, K. H. S.; Deacy, A. C.; Williams, C. K. Synergic Catalysis: the Importance of Intermetallic Separation in Co(III)K(I) Catalysts for Ring Opening Copolymerizations. Journal of the American Chemical Society 2024, 146, 23517–23528. doi:10.1021/jacs.4c07405
  • Yang, L.; Liu, S.; Fan, P.; Gao, F.; Pang, X.; Chen, X.; Wang, X. Highly active aggregate catalysts for the synthesis of high-molecular-weight polyesters via copolymerization of epoxides and cyclic anhydrides. Polymer Chemistry 2024, 15, 2482–2491. doi:10.1039/d4py00432a
  • Zhao, T.; Chen, S.; Huang, X.; Yin, J.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Xiao, M.; Meng, Y. Metal-Free Synthesis of Biodegradable CO2-Based Oligo(carbonate-ester) Diols as Building Blocks for Thermoplastic Polyurethanes. ACS Applied Polymer Materials 2024, 6, 1813–1822. doi:10.1021/acsapm.3c02652
  • Shellard, E. J. K.; Diment, W. T.; Resendiz-Lara, D. A.; Fiorentini, F.; Gregory, G. L.; Williams, C. K. Al(III)/K(I) Heterodinuclear Polymerization Catalysts Showing Fast Rates and High Selectivity for Polyester Polyols. ACS catalysis 2024, 14, 1363–1374. doi:10.1021/acscatal.3c05712
  • Suo, H.; Tang, H.; Qu, R.; Liu, J.; Qin, Y. Sustainable polycarbonates production from CO2. Advances in Bioenergy; Elsevier, 2024; pp 171–246. doi:10.1016/bs.aibe.2024.03.001
  • Wang, H.; Ma, H. Ring-opening Copolymerization of Epoxides and Anhydride Mediated by Claw-type Aminophenolate Zinc Chlorides. Acta Chimica Sinica 2024, 82, 577. doi:10.6023/a24040122
  • Xu, X.; Li, H.; Mehmood, A.; Chi, K.; Shi, D.; Wang, Z.; Wang, B.; Li, Y.; Luo, Y. Mechanistic Studies on Aluminum-Catalyzed Ring-Opening Alternating Copolymerization of Maleic Anhydride with Epoxides: Ligand Effects and Quantitative Structure-Activity Relationship Model. Molecules (Basel, Switzerland) 2023, 28, 7279. doi:10.3390/molecules28217279
  • Niknam, F.; Denk, A.; Buonerba, A.; Rieger, B.; Grassi, A.; Capacchione, C. Dinuclear chromium complexes with [OSSO]-type ligands in the copolymerization of epoxides with CO2and phthalic anhydride. Catalysis Science & Technology 2023, 13, 4684–4692. doi:10.1039/d3cy00832k
  • Manjarrez, Y.; Clark, A. M.; Fieser, M. E. Rare Earth Metal‐Containing Ionic Liquid Catalysts for Synthesis of Epoxide/Cyclic Anhydride Copolymers. ChemCatChem 2023, 15. doi:10.1002/cctc.202300319
  • Liang, J.; Wang, S.; Wu, C.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Xiao, M.; Meng, Y. A new biodegradable CO2-based poly(ester-co-carbonate): Molecular chain building up with crosslinkable domain. Journal of CO2 Utilization 2023, 69, 102403. doi:10.1016/j.jcou.2023.102403
  • Haslewood, M. N. D.; Farmer, T. J.; North, M. Synthesis and chemoselective crosslinking of functionalized polyesters from bio‐based epoxides and cyclic anhydrides. Journal of Polymer Science 2022, 61, 311–322. doi:10.1002/pol.20220552
  • Wood, Z. A.; Assefa, M. K.; Fieser, M. E. Simple yttrium salts as highly active and controlled catalysts for the atom-efficient synthesis of high molecular weight polyesters. Chemical science 2022, 13, 10437–10447. doi:10.1039/d2sc02745c
  • Wang, Z.; Yin, G.; Wang, Z.; Yin, Y. Synthesis of anionic rare-earth metal salan complexes as catalysts for copolymerization of cyclohexene oxide with cyclic anhydrides. Inorganic Chemistry Communications 2022, 143, 109805. doi:10.1016/j.inoche.2022.109805
  • Lidston, C. A. L.; Severson, S. M.; Abel, B. A.; Coates, G. W. Multifunctional Catalysts for Ring-Opening Copolymerizations. ACS Catalysis 2022, 12, 11037–11070. doi:10.1021/acscatal.2c02524
  • Liang, J.; Ye, S.; Wang, S.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Liu, W.; Xiao, M.; Sun, L.; Meng, Y. Biodegradable Copolymers from CO2, Epoxides, and Anhydrides Catalyzed by Organoborane/Tertiary Amine Pairs: High Selectivity and Productivity. Macromolecules 2022, 55, 6120–6130. doi:10.1021/acs.macromol.2c01118
  • Cui, L.; Liu, Y.; Ren, B.-H.; Lu, X.-B. Preparation of Sequence-Controlled Polyester and Polycarbonate Materials via Epoxide Copolymerization Mediated by Trinuclear Co(III) Complexes. Macromolecules 2022, 55, 3541–3549. doi:10.1021/acs.macromol.2c00501
  • Manjarrez, Y.; Cheng-Tan, M. D. C. L.; Fieser, M. E. Perfectly Alternating Copolymerization of Cyclic Anhydrides and Epoxides with Yttrium β-Diketiminate Complexes. Inorganic chemistry 2022, 61, 7088–7094. doi:10.1021/acs.inorgchem.2c00529
  • Wang, Y.; Wang, M.; Shi, Y.; Chen, X.; Song, D.; Li, Y.; Wang, B. Switchable Copolymerization of Maleic Anhydride/Epoxides/Lactide Mixtures: A Straightforward Approach to Block Copolymers with Unsaturated Polyester Sequences. Macromolecular Chemistry and Physics 2022, 223. doi:10.1002/macp.202200079
  • Chen, X.-L.; Wang, B.; Pan, L.; Li, Y.-S. Synthesis of Unsaturated (Co)polyesters from Ring-Opening Copolymerization by Aluminum Bipyridine Bisphenolate Complexes with Improved Protonic Impurities Tolerance. Macromolecules 2022, 55, 3502–3512. doi:10.1021/acs.macromol.2c00034

Patents

  • WEI HUAIJIAN; LI HONGGUO; LI YIGE; GAO YUFEI; FU HAI; DONG LIANG. METHOD FOR PREPARING CARBON DIOXIDE-BASED QUATERNARY COPOLYMER. WO 2023045887 A1, March 30, 2023.
  • LI HONGGUO; WANG XUNLIN; LI YIGE; ZHANG JUNLING; GAO SHEN; HU WENDA. CARBON DIOXIDE COPOLYMER COMPOSITION AND PREPARATION METHOD THEREFOR. WO 2023045888 A1, March 30, 2023.
  • KEMBER MICHAEL; LEELAND JAMES; RILEY KERRY. (POLY)OL BLOCK COPOLYMER. WO 2022096889 A1, May 12, 2022.
Other Beilstein-Institut Open Science Activities