Synthesis and structures of ruthenium–NHC complexes and their catalysis in hydrogen transfer reaction

Scholarly Works

• He, F.; Zois, K. P.; Tzeli, D.; Danopoulos, A. A.; Braunstein, P. N-heterocyclic carbenes as bridgehead donors in metal pincer complexes. Coordination Chemistry Reviews 2024, 514, 215757. doi:10.1016/j.ccr.2024.215757
• Chernenko, A. Y.; Shepelenko, K. E.; Minyaev, M. E.; Chernyshev, V. M. Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones. Mendeleev Communications 2024, 34, 385–388. doi:10.1016/j.mencom.2024.04.023
• Mayr, J.; Reich, R. M.; Kühn, F. E. Ru(II) complexes with phosphine-functionalized NHC ligands in catalytic transfer hydrogenations. Advances in Organometallic Chemistry; Elsevier, 2023; pp 135–156. doi:10.1016/bs.adomc.2022.12.002
• Ritleng, V.; Michon, C. Bidentate Donor-Functionalized N-Heterocyclic Carbenes: Valuable Ligands for Ruthenium-Catalyzed Transfer Hydrogenation. Molecules (Basel, Switzerland) 2022, 27, 4703. doi:10.3390/molecules27154703
• Wu, W.-C.; Hu, L.-L.; Wang, L.-X.; Zhang, X.; Xiang, J. Synthesis, crystal structures and kinetics of two paramagnetic osmium(III) phosphoranimine complexes from high-valent osmium(VI) nitrides. Inorganic Chemistry Communications 2022, 138, 109244. doi:10.1016/j.inoche.2022.109244
• Böth, A. D.; Sauer, M. J.; Reich, R. M.; Kühn, F. E. Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands. Comprehensive Organometallic Chemistry IV; Elsevier, 2022; pp 444–527. doi:10.1016/b978-0-12-820206-7.00142-6
• Sadimenko, A. P. Organometallic complexes of functionalized chelating azines: Part 2. Advances in Heterocyclic Chemistry; Elsevier, 2021; Vol. 133, pp 225–288. doi:10.1016/bs.aihch.2020.05.001
• Wei, W.; Jia, G. Comprehensive Coordination Chemistry III - Metal-Carbon Bonds of Heavier Group 7 and 8 Metals (Tc, Re, Ru, Os): Mononuclear Tc/Re/Ru/Os Complexes With Metal-Carbon Bonds. Comprehensive Coordination Chemistry III; Elsevier, 2021; pp 123–439. doi:10.1016/b978-0-08-102688-5.00049-0
• Wang, Y.; Jin, J.; Shu, L.; Li, T.; Lu, S.; Subarkhan, M. K. M.; Chen, C.; Wang, H. New Organometallic Ruthenium(II) Compounds Synergistically Show Cytotoxic, Antimetastatic and Antiangiogenic Activities for the Treatment of Metastatic Cancer. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 26, 15170–15182. doi:10.1002/chem.202002970
• Kaloğlu, N. N-heterocyclic carbene based ruthenium complexes for selective β-C(sp3)-H functionalization of N-fused saturated cyclic amines. Tetrahedron 2019, 75, 2265–2272. doi:10.1016/j.tet.2018.12.049
• Şahin, N.; Şahin-Bölükbaşı, S.; Tahir, M.; Arıcı, C.; Çevik, E.; Gürbüz, N.; Özdemir, İ.; Cummings, B. S. Synthesis, characterization and anticancer activity of allyl substituted N-Heterocyclic carbene silver(I) complexes. Journal of Molecular Structure 2019, 1179, 92–99. doi:10.1016/j.molstruc.2018.10.094
• Abubakar, S.; Ibrahim, H.; Bala, M. D. Transfer hydrogenation of ketones catalyzed by a trinuclear Ni(II) complex of a Schiff base functionalized N-heterocyclic carbene ligand. Inorganica Chimica Acta 2019, 484, 276–282. doi:10.1016/j.ica.2018.09.057
• Junwei, Z.; Lu, X. L. Crystal structure of trans-tetrakis(acetonitrile-κN)bis(triphenylphosphine-κP)ruthenium(II) dihexafluorophosphate - dichloroform (1/2), C46H44Cl6F12N4P4Ru. Zeitschrift für Kristallographie - New Crystal Structures 2018, 234, 425–427. doi:10.1515/ncrs-2018-0430
• Hey, D. A.; Reich, R. M.; Baratta, W.; Kühn, F. E. Current advances on ruthenium(II) N-heterocyclic carbenes in hydrogenation reactions. Coordination Chemistry Reviews 2018, 374, 114–132. doi:10.1016/j.ccr.2018.06.005
• Jiang, Y.; Gendy, C.; Roesler, R. Nickel, Ruthenium, and Rhodium NCN-Pincer Complexes Featuring a Six-Membered N-Heterocyclic Carbene Central Moiety and Pyridyl Pendant Arms. Organometallics 2018, 37, 1123–1132. doi:10.1021/acs.organomet.8b00022
• Kaloğlu, M.; Gürbüz, N.; Sémeril, D.; Özdemir, İ. Ruthenium(II)‐(p‐cymene)‐N‐Heterocyclic Carbene Complexes for the N‐Alkylation of Amine Using the Green Hydrogen Borrowing Methodology. European Journal of Inorganic Chemistry 2018, 2018, 1236–1243. doi:10.1002/ejic.201701479
• Abbas, M. A.; McMillen, C. D.; Brumaghim, J. L. Synthesis, characterization, and structures of ruthenium(II) complexes with multiple solvato ligands. Inorganica Chimica Acta 2017, 468, 308–315. doi:10.1016/j.ica.2017.07.003
• Olguín, J.; Paz-Sandoval, M. A. Synthesis and transfer hydrogenation catalysis of chelating triazolylidene ruthenium(II) complexes: Effect of the pendant arm, p-cymene, acetonitrile and butadienesulfonyl co-ligands. Journal of Organometallic Chemistry 2017, 848, 309–317. doi:10.1016/j.jorganchem.2017.08.012
• Chen, C.; Ni, S.; Zheng, Q.; Yu, M.; Wang, H. Synthesis, Structure, Biological Evaluation, and Catalysis of Two Pyrazole‐Functionalized NHC–RuII Complexes. European Journal of Inorganic Chemistry 2017, 2017, 616–622. doi:10.1002/ejic.201601116
• Olguín, J.; Díaz-Fernández, M.; de la Cruz-Cruz, J. I.; Paz-Sandoval, M. A. Mixed heteropentadienyl and N-heterocyclic carbene ruthenium(II) complexes: Synthesis and transfer hydrogenation catalysis. Journal of Organometallic Chemistry 2016, 824, 33–41. doi:10.1016/j.jorganchem.2016.09.031

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