Nitro-Grela-type complexes containing iodides – robust and selective catalysts for olefin metathesis under challenging conditions

Scholarly Works

• Morita, I.; Ward, T. R. Recent advances in the design and optimization of artificial metalloenzymes. Current opinion in chemical biology 2024, 81, 102508. doi:10.1016/j.cbpa.2024.102508
• Ingram, A. A.; Wang, D.; Schwaneberg, U.; Okuda, J. Grubbs-Hoveyda catalysts conjugated to a β-barrel protein: Effect of halide substitution on aqueous olefin metathesis activity. Journal of inorganic biochemistry 2024, 258, 112616. doi:10.1016/j.jinorgbio.2024.112616
• Nasibullin, I.; Yoshioka, H.; Mukaimine, A.; Nakamura, A.; Kusakari, Y.; Chang, T.-C.; Tanaka, K. Catalytic olefin metathesis in blood. Chemical science 2023, 14, 11033–11039. doi:10.1039/d3sc03785a
• Nechmad, N. B.; Iudanov, K.; Tarannam, N.; Kobernik, V.; Kozuch, S.; Lemcoff, N. G. Coordinating Additives as Activity Modulators in Diiodo Latent Olefin Metathesis Catalysts. ChemCatChem 2023, 15. doi:10.1002/cctc.202201690
• Alassad, N.; Nechmad, N. B.; Phatake, R. S.; Reany, O.; Lemcoff, N. G. Steric and electronic effects in latent S-chelated olefin metathesis catalysts. Catalysis Science & Technology 2023, 13, 321–328. doi:10.1039/d2cy00943a
• Jawiczuk, M.; Kuźmierkiewicz, N.; Nowacka, A. M.; Moreń, M.; Trzaskowski, B. Mechanistic, Computational Study of Alkene-Diazene Heterofunctional Cross-Metathesis Catalyzed by Ruthenium Complexes. Organometallics 2023, 42, 146–156. doi:10.1021/acs.organomet.2c00516
• Blanco, C. O.; Fogg, D. E. Water-Accelerated Decomposition of Olefin Metathesis Catalysts. ACS catalysis 2023, 13, 1097–1102. doi:10.1021/acscatal.2c05573
• Leyva-Pérez, A.; Garnes-Portolés, F.; Sánchez-Quesada, J.; Espinós-Ferri, E. Synthesis of Dehydromuscone by an Alkene Metathesis Macrocyclization Reaction at 0.2 M Concentration. Synlett 2022, 33, 1933–1937. doi:10.1055/a-1932-9317
• Phatake, R. S.; Nechmad, N. B.; Reany, O.; Lemcoff, N. G. Highly Substrate‐Selective Macrocyclic Ring Closing Metathesis. Advanced Synthesis & Catalysis 2022, 364, 1465–1472. doi:10.1002/adsc.202101515
• Saied, E. M.; Arenz, C. Stereoselective Synthesis of Novel Sphingoid Bases Utilized for Exploring the Secrets of Sphinx. International journal of molecular sciences 2021, 22, 8171. doi:10.3390/ijms22158171
• Nascimento, D. L.; Foscato, M.; Occhipinti, G.; Jensen, V. R.; Fogg, D. E. Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium-Carbene Catalysts. Journal of the American Chemical Society 2021, 143, 11072–11079. doi:10.1021/jacs.1c04424
• Blanco, C. O.; Nascimento, D. L.; Fogg, D. E. Routes to High-Performing Ruthenium-Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange. Organometallics 2021, 40, 1811–1816. doi:10.1021/acs.organomet.1c00253
• Patra, S. G.; Das, N. K. Recent advancement on the mechanism of olefin metathesis by Grubbs catalysts: A computational perspective. Polyhedron 2021, 200, 115096. doi:10.1016/j.poly.2021.115096
• Nechmad, N. B.; Kobernik, V.; Tarannam, N.; Phatake, R.; Eivgi, O.; Kozuch, S.; Lemcoff, N. G. Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts. Angewandte Chemie 2021, 133, 6442–6446. doi:10.1002/ange.202014929
• Nechmad, N. B.; Kobernik, V.; Tarannam, N.; Phatake, R. S.; Eivgi, O.; Kozuch, S.; Lemcoff, N. G. Reactivity and Selectivity in Ruthenium Sulfur‐Chelated Diiodo Catalysts. Angewandte Chemie (International ed. in English) 2021, 60, 6372–6376. doi:10.1002/anie.202014929
• Blanco, C. O.; Sims, J. M.; Nascimento, D. L.; Goudreault, A. Y.; Steinmann, S. N.; Michel, C.; Fogg, D. E. The Impact of Water on Ru-Catalyzed Olefin Metathesis: Potent Deactivating Effects Even at Low Water Concentrations. ACS catalysis 2021, 11, 893–899. doi:10.1021/acscatal.0c04279
• Kajetanowicz, A.; Grela, K. Durch Nitro- und andere elektronenziehende Gruppen aktivierte Ruthenium-Katalysatoren für die Olefinmetathese. Angewandte Chemie 2020, 133, 13854–13873. doi:10.1002/ange.202008150
• Kajetanowicz, A.; Grela, K. Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions. Angewandte Chemie (International ed. in English) 2020, 60, 13738–13756. doi:10.1002/anie.202008150
• Pieczykolan, M.; Czaban-Jóźwiak, J.; Malinska, M.; Woźniak, K.; Dorta, R.; Rybicka, A.; Kajetanowicz, A.; Grela, K. The Influence of Various N-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts. Molecules (Basel, Switzerland) 2020, 25, 2282. doi:10.3390/molecules25102282
• Breen, C. P.; Parrish, C.; Shangguan, N.; Majumdar, S.; Murnen, H.; Jamison, T. F.; Bio, M. M. A Scalable Membrane Pervaporation Approach for Continuous Flow Olefin Metathesis. Organic Process Research & Development 2020, 24, 2298–2303. doi:10.1021/acs.oprd.0c00061

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