Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands

Johnathon Yau, Kaarel E. Hunt, Laura McDougall, Alan R. Kennedy and David J. Nelson
Beilstein J. Org. Chem. 2015, 11, 2171–2178. https://doi.org/10.3762/bjoc.11.235

Supporting Information

Supporting Information File 1: Crystal structure data for new complexes.
Format: CIF Size: 47.6 KB Download
Supporting Information File 2: NMR spectra for compounds and complexes.
Format: PDF Size: 456.9 KB Download

Cite the Following Article

Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands
Johnathon Yau, Kaarel E. Hunt, Laura McDougall, Alan R. Kennedy and David J. Nelson
Beilstein J. Org. Chem. 2015, 11, 2171–2178. https://doi.org/10.3762/bjoc.11.235

How to Cite

Yau, J.; Hunt, K. E.; McDougall, L.; Kennedy, A. R.; Nelson, D. J. Beilstein J. Org. Chem. 2015, 11, 2171–2178. doi:10.3762/bjoc.11.235

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Daniel, S.; Vijayakumar, M.; Gandigawad, A.; Dateer, R. B.; Budagumpi, S. Nickel(II)–N-Heterocyclic Carbene Complex and its Carbon Nanotube Composites as Efficient Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution Reactions and Mercury-Sensing Applications. Energy & Fuels 2024, 38, 14632–14644. doi:10.1021/acs.energyfuels.4c01848
  • Włodzimierz, B. Cyclopentadienyl Nickel Complexes. Comprehensive Organometallic Chemistry IV; Elsevier, 2022; pp 357–426. doi:10.1016/b978-0-12-820206-7.00104-9
  • Sarmah, D.; Saikia, R.; Bora, U. An attractive avenue to Chan-Lam cross-coupling: Scope and developments under Ni-catalysis. Tetrahedron 2022, 104, 132567. doi:10.1016/j.tet.2021.132567
  • Ma, X.; Guillet, S. G.; Liu, Y.; Cazin, C. S. J.; Nolan, S. P. Simple synthesis of [Ru(CO3)(NHC)(p-cymene)] complexes and their use in transfer hydrogenation catalysis. Dalton transactions (Cambridge, England : 2003) 2021, 50, 13012–13019. doi:10.1039/d1dt02098f
  • Chesnokov, V. V.; Shevchenko, M. A.; Soliev, S. B.; Tafeenko, V. A.; Chernyshev, V. M. Complexes LNi(Cp)X with alkylamino-substituted N-heterocyclic carbene ligands (L) and their catalytic activity in the Suzuki—Miyaura reaction. Russian Chemical Bulletin 2021, 70, 1281–1289. doi:10.1007/s11172-021-3212-5
  • Mazars, F.; Hrubaru, M.; Tumanov, N.; Wouters, J.; Delaude, L. Synthesis of Azolium-2-dithiocarboxylate Zwitterions under Mild, Aerobic Conditions. European Journal of Organic Chemistry 2021, 2021, 2025–2033. doi:10.1002/ejoc.202100274
  • Ulm, F.; Cornaton, Y.; Djukic, J.-P.; Chetcuti, M. J.; Ritleng, V. Hydroboration of Alkenes Catalysed by a Nickel N-Heterocyclic Carbene Complex: Reaction and Mechanistic Aspects. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 26, 8916–8925. doi:10.1002/chem.202000289
  • Banach, Ł.; Guńka, P. A.; Zachara, J.; Buchowicz, W. Half-sandwich Ni(II) complexes [Ni(Cp)(X)(NHC)]: From an underestimated discovery to a new chapter in organonickel chemistry. Coordination Chemistry Reviews 2019, 389, 19–58. doi:10.1016/j.ccr.2019.03.006
  • Ando, S.; Hirota, Y.; Matsunaga, H.; Ishizuka, T. Nickel-catalyzed N-arylation of amines with arylboronic acids under open air. Tetrahedron Letters 2019, 60, 1277–1280. doi:10.1016/j.tetlet.2019.04.004
  • Trampert, J.; Nagel, M.; Grimm, T.; Sun, Y.; Thiel, W. R. Phosphine Functionalized NHC Ligands and Their Cyclopentadienide Nickel(II) Complexes. Zeitschrift für anorganische und allgemeine Chemie 2018, 644, 963–972. doi:10.1002/zaac.201800151
  • Li, G.; Lei, P.; Szostak, M.; Casals-Cruañas, È.; Poater, A.; Cavallo, L.; Nolan, S. P. Mechanistic Study of Suzuki–Miyaura Cross-Coupling Reactions of Amides Mediated by [Pd(NHC)(allyl)Cl] Precatalysts. ChemCatChem 2018, 10, 3096–3106. doi:10.1002/cctc.201800511
  • Włodarska, A.; Gołaszewska-Gajda, J.; Dranka, M.; Pietrzykowski, A. Synthesis, characterization and catalytic activity of nickel NHC complexes. Molecular Catalysis 2017, 440, 25–35. doi:10.1016/j.mcat.2017.06.033
  • Meconi, G. M.; Vummaleti, S. V. C.; Luque-Urrutia, J. A.; Belanzoni, P.; Nolan, S. P.; Jacobsen, H.; Cavallo, L.; Solà, M.; Poater, A. Mechanism of the Suzuki–Miyaura Cross-Coupling Reaction Mediated by [Pd(NHC)(allyl)Cl] Precatalysts. Organometallics 2017, 36, 2088–2095. doi:10.1021/acs.organomet.7b00114
  • Gómez-Suárez, A.; Nelson, D. J.; Nolan, S. P. Quantifying and understanding the steric properties of N-heterocyclic carbenes. Chemical communications (Cambridge, England) 2017, 53, 2650–2660. doi:10.1039/c7cc00255f
  • Ando, S.; Matsunaga, H.; Ishizuka, T. An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki–Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids. The Journal of organic chemistry 2017, 82, 1266–1272. doi:10.1021/acs.joc.6b02666
  • Teo, W. J.; Wang, Z.; Xue, F.; Hor, T. S. A.; Zhao, J. Cyclopentadienyl nickel(ii) N,C-chelating benzothiazolyl NHC complexes: synthesis, characterization and application in catalytic C-C bond formation reactions. Dalton transactions (Cambridge, England : 2003) 2016, 45, 7312–7319. doi:10.1039/c6dt00252h
Other Beilstein-Institut Open Science Activities