Catalytic asymmetric formal synthesis of beraprost

Scholarly Works

• Kobayashi, Y.; Takemoto, Y. Olefins Hydrofunctionnalization; Hydroamination and Hydroalcoxylation of Electron-Deficient Olefins. Comprehensive Chirality; Elsevier, 2024; pp 151–196. doi:10.1016/b978-0-32-390644-9.00049-4
• Hommelsheim, R.; van Nahl, R.; Hanek, L. M.; Ward, J. S.; Rissanen, K.; Bolm, C. Palladium‐Catalyzed Domino Reaction for the Synthesis of 3‐Amino 1,2,4‐Benzothiadiazine 1,1‐Dioxides. Advanced Synthesis & Catalysis 2023, 366, 717–724. doi:10.1002/adsc.202300875
• Su, G.; Formica, M.; Yamazaki, K.; Hamlin, T. A.; Dixon, D. J. Catalytic Enantioselective Intramolecular Oxa-Michael Reaction to α,β-Unsaturated Esters and Amides. Journal of the American Chemical Society 2023, 145, 12771–12782. doi:10.1021/jacs.3c03182
• Serusi, L.; Palombi, L.; Pierri, G.; Mola, A. D.; Massa, A. Asymmetric Cascade Aza-Henry/Lactamization Reaction in the Highly Enantioselective Organocatalytic Synthesis of 3-(Nitromethyl)isoindolin-1-ones from α-Amido Sulfones. The Journal of organic chemistry 2022, 87, 8420–8428. doi:10.1021/acs.joc.2c00518
• Pan, Y.-L.; Shao, Y.-B.; Wang, J.; Liu, Z.; Chen, L.; Li, X. Kinetic Resolution of 2H-Azirines by Asymmetric Allylation Reactions. ACS Catalysis 2021, 11, 13752–13760. doi:10.1021/acscatal.1c03875
• Takemoto, Y.; Tokuhiro, Y.; Hayama, N.; Kobayashi, Y. Bifunctional-Benzothiadiazine-Catalyzed Regio- and Stereoselective Aldol Reactions Using A 1,3-Acetonedicarboxylic Acid Monoester. HETEROCYCLES 2021, 103, 484. doi:10.3987/com-20-s(k)12
• Pentsak, E. O.; Galushko, A. S.; Shaydullin, R. R.; Ananikov, V. P. Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium. Russian Chemical Bulletin 2020, 69, 1185–1188. doi:10.1007/s11172-020-2887-3
• Xie, W.-B.; Li, Z. Asymmetric Synthesis of Ethers by Catalytic Alkene Hydro­alkoxy­lation. Synthesis 2020, 52, 2127–2146. doi:10.1055/s-0039-1690874
• Nanjo, T.; Zhang, X.; Tokuhiro, Y.; Takemoto, Y. Divergent and Scalable Synthesis of α-Hydroxy/Keto-β-amino Acid Analogues by the Catalytic Enantioselective Addition of Glyoxylate Cyanohydrin to Imines. ACS Catalysis 2019, 9, 10087–10092. doi:10.1021/acscatal.9b03394
• Watanabe, K.; Mino, T.; Masuda, C.; Yoshida, Y.; Sakamoto, M. Synthesis of 7-Allylated Benzofuran Derivatives from o-Allyloxyethynylbenzene via Claisen Rearrangement and TBAF-Catalyzed Annulation. European Journal of Organic Chemistry 2019, 2019, 1635–1645. doi:10.1002/ejoc.201801800
• Zhu, H.-t.; Yang, H.; Zhan, L.; Liu, T.; Shiqiong, Y.; Kang, L.-t.; Luo, Y. A Practical Synthesis of a Key Intermediate of Beraprost. Journal of Chemical Research 2018, 42, 105–108. doi:10.3184/174751918x15190387567113
• Yakura, T.; Nambu, H. Recent topics in application of selective Rh(II)-catalyzed CH functionalization toward natural product synthesis. Tetrahedron Letters 2018, 59, 188–202. doi:10.1016/j.tetlet.2017.12.027
• Peng, H.; Chen, F.-E. Recent advances in asymmetric total synthesis of prostaglandins. Organic & biomolecular chemistry 2017, 15, 6281–6301. doi:10.1039/c7ob01341h
• Umemiya, S.; Sakamoto, D.; Kawauchi, G.; Hayashi, Y. Enantioselective Total Synthesis of Beraprost Using Organocatalyst. Organic letters 2017, 19, 1112–1115. doi:10.1021/acs.orglett.7b00134
• Orue, A.; Uria, U.; Roca-López, D.; Delso, J. I.; Reyes, E.; Carrillo, L.; Merino, P.; Vicario, J. L. Racemic hemiacetals as oxygen-centered pronucleophiles triggering cascade 1,4-addition/Michael reaction through dynamic kinetic resolution under iminium catalysis. Development and mechanistic insights. Chemical science 2017, 8, 2904–2913. doi:10.1039/c7sc00009j
• 张剑; 魏一飞; 罗人仕. 酚参与的不对称C-O键形成研究进展 Progress on Asymmetric C-O Bond Formation with Phenols. Journal of Organic Chemistry Research 2017, 05, 51–69. doi:10.12677/jocr.2017.51008
• Liu, X.; Tian, C.; Jiao, X.; Li, X.; Yang, H.; Yao, Y.; Xie, P. A practical synthesis of chiral tricyclic cyclopenta[b]benzofuran, a key intermediate of Beraprost. Organic & biomolecular chemistry 2016, 14, 7715–7721. doi:10.1039/c6ob01346e
• Kobayashi, Y.; Kuramoto, R.; Takemoto, Y. Catalytic Asymmetric Formal Synthesis of Beraprost. ChemInform 2016, 47. doi:10.1002/chin.201609129

Explore citations to this article at