Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules

Scholarly Works

• He, F.; Zois, K. P.; Tzeli, D.; Danopoulos, A. A.; Braunstein, P. N-heterocyclic carbenes as bridgehead donors in metal pincer complexes. Coordination Chemistry Reviews 2024, 514, 215757. doi:10.1016/j.ccr.2024.215757
• Shi, H.; Yue, G.; Yan, P.; Ji, X.; Wei, Y.; Song, H.; Jia, X. A new method for synthesizing terminal olefins from esters using the Corey-Chaykovsky reagent. Organic & biomolecular chemistry 2024, 22, 5093–5096. doi:10.1039/d4ob00620h
• Papangelis, E.; Pelzer, K.; Gourlaouen, C.; Armspach, D.; Braunstein, P.; Danopoulos, A. A.; Bailly, C.; Tsoureas, N.; Gerokonstantis, D. T. New Pyridine Dicarbene Pincer Ligands with Ring Expanded NHCs and their Nickel and Chromium Complexes. Chemistry, an Asian journal 2024, 19, e202400169. doi:10.1002/asia.202400169
• Tzeliou, C. E.; Zois, K. P.; Tzeli, D. Molecular Logic Gates Based on Ferrocene-Containing Compounds. Inorganics 2024, 12, 106. doi:10.3390/inorganics12040106
• Vita, D. E.; Schiel, M. A.; Lo Fiego, M. J.; Silbestri, G. F. Anionic N-Heterocyclic Carbene Gold(I) Complexes from Sydnones as a Precarbenic Unit: A Comprehensive Study of the Au–C sp2 Bond Stability Compared to Its "Relative" Imidazole. Organometallics 2023, 43, 191–201. doi:10.1021/acs.organomet.3c00486
• Kumar, R.; Pandey, M. K.; Pandey, I. K.; Kumar, A.; Choudhury, J. An Imidazolylidene‐Based Mesoionic Carbene–Mn(I) Complex and Its Catalytic Potential in N‐Heteroarene Hydrogenation. European Journal of Inorganic Chemistry 2023, 26. doi:10.1002/ejic.202300411
• Bouma, M. J.; Aspers, R. L. E. G.; Tessari, M.; Rutjes, F. P. J. T.; Fraser, R.; Feiters, M. C. Computational (DFT) and Experimental (NMR) Study of the Chelation of an Iridium Hyperpolarization Transfer Catalyst by Amino Acids. European Journal of Inorganic Chemistry 2023, 26. doi:10.1002/ejic.202300260
• Tiemann, M. A. Ph.D. Thesis, University of North Texas Libraries, July 1, 2023. doi:10.12794/metadc2179238
• Ghadwal, R. S. 1,3‐Imidazol‐basierte mesoionische Carbene und anionische Dicarbene: Erweiterung der Grenzen klassischer N‐heterocyclischer Carbene. Angewandte Chemie 2023, 135. doi:10.1002/ange.202304665
• Ghadwal, R. S. 1,3-Imidazole-Based Mesoionic Carbenes and Anionic Dicarbenes: Pushing the Limit of Classical N-Heterocyclic Carbenes. Angewandte Chemie (International ed. in English) 2023, 62, e202304665. doi:10.1002/anie.202304665
• Jabłoński, M. Halogen Bond to Experimentally Significant N-Heterocyclic Carbenes (I, IMe2, IiPr2, ItBu2, IPh2, IMes2, IDipp2, IAd2; I = Imidazol-2-ylidene). International journal of molecular sciences 2023, 24, 9057. doi:10.3390/ijms24109057
• Sagan, F.; Mitoraj, M.; Jabłoński, M. Nature of Beryllium, Magnesium, and Zinc Bonds in Carbene⋯MX2 (M = Be, Mg, Zn; X = H, Br) Dimers Revealed by the IQA, ETS-NOCV and LED Methods. International journal of molecular sciences 2022, 23, 14668. doi:10.3390/ijms232314668
• Muthig, A. M. T.; Krumrein, M.; Wieland, J.; Gernert, M.; Kerner, F.; Pflaum, J.; Steffen, A. Trigonal Copper(I) Complexes with Cyclic (Alkyl)(amino)carbene Ligands for Single-Photon Near-IR Triplet Emission. Inorganic chemistry 2022, 61, 14833–14844. doi:10.1021/acs.inorgchem.2c02376
• Rahman, M. M.; Zhang, J.; Zhao, Q.; Feliciano, J.; Bisz, E.; Dziuk, B.; Lalancette, R.; Szostak, R.; Szostak, M. Pd-PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions. Organometallics 2022, 41, 2281–2290. doi:10.1021/acs.organomet.2c00262
• Banerjee, S.; Vanka, K. Computational insights into hydroboration with acyclic α-Borylamido-germylene and stannylene catalysts: Cooperative dual catalysis the key to system efficiency. Polyhedron 2022, 222, 115907. doi:10.1016/j.poly.2022.115907
• Seed, J. A.; Vondung, L.; Adams, R. W.; Wooles, A. J.; Lu, E.; Liddle, S. T. Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV). Organometallics 2022, 41, 1353–1363. doi:10.1021/acs.organomet.2c00120
• Silva, J. G.; de Miranda, A. S.; Ismail, F. M. D.; Barbosa, L. C. A. Synthesis and medicinal chemistry of tetronamides: Promising agrochemicals and antitumoral compounds. Bioorganic & medicinal chemistry 2022, 67, 116815. doi:10.1016/j.bmc.2022.116815
• Sorbelli, D.; Belpassi, L.; Belanzoni, P. Unraveling differences in aluminyl and carbene coordination chemistry: bonding in gold complexes and reactivity with carbon dioxide. Chemical science 2022, 13, 4623–4634. doi:10.1039/d2sc00630h
• Zhang, J.; Rahman, M.; Zhao, Q.; Feliciano, J.; Bisz, E.; Dziuk, B.; Lalancette, R.; Szostak, R.; Szostak, M. N-Heterocyclic Carbene Complexes of Nickel(II) from Caffeine and Theophylline: Sustainable Alternative to Imidazol-2-ylidenes. Organometallics 2022, 41, 1806–1815. doi:10.1021/acs.organomet.2c00019
• Golzadeh, B.; Kazeri-shandiz, S.; Akbari, A. On the nature of M L bond and the puckering of some B-heterocyclic carbenes and silylenes in their relevant complexes with coinage metals: A theoretical quest. Journal of Molecular Structure 2022, 1252, 132192. doi:10.1016/j.molstruc.2021.132192

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