Enantioconvergent catalysis

Justin T. Mohr, Jared T. Moore and Brian M. Stoltz
Beilstein J. Org. Chem. 2016, 12, 2038–2045. https://doi.org/10.3762/bjoc.12.192

Cite the Following Article

Enantioconvergent catalysis
Justin T. Mohr, Jared T. Moore and Brian M. Stoltz
Beilstein J. Org. Chem. 2016, 12, 2038–2045. https://doi.org/10.3762/bjoc.12.192

How to Cite

Mohr, J. T.; Moore, J. T.; Stoltz, B. M. Beilstein J. Org. Chem. 2016, 12, 2038–2045. doi:10.3762/bjoc.12.192

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 118.5 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Preinfalk, A.; Oost, R.; Menger, M. F. S. J.; Simaan, M.; Lemouzy, S.; Senoner, S.; Shaaban, S.; Maryasin, B.; González, L.; Maulide, N. Enantioconvergent Negishi Cross-Couplings of Racemic Secondary Organozinc Reagents to Access Privileged Scaffolds: A Combined Experimental and Theoretical Study. Angewandte Chemie (International ed. in English) 2024, e202414868. doi:10.1002/anie.202414868
  • Preinfalk, A.; Oost, R.; Menger, M. F. S. J.; Simaan, M.; Lemouzy, S.; Senoner, S.; Shaaban, S.; Maryasin, B.; González, L.; Maulide, N. Enantiokonvergente Negishi‐Kreuzkupplungen von Racemischen Sekundären Organozink‐Reagenzien zur Herstellung Privilegierter Gerüste: Eine Kombinierte Experimentelle und Theoretische Studie. Angewandte Chemie 2024. doi:10.1002/ange.202414868
  • Vu, J.; Haug, G. C.; Li, Y.; Zhao, B.; Chang, C. J.; Paton, R. S.; Dong, Y. Enantioconvergent Cross‐Nucleophile Coupling: Copper‐Catalyzed Deborylative Cyanation. Angewandte Chemie 2024. doi:10.1002/ange.202408745
  • Vu, J.; Haug, G. C.; Li, Y.; Zhao, B.; Chang, C. J.; Paton, R. S.; Dong, Y. Enantioconvergent Cross-Nucleophile Coupling: Copper-Catalyzed Deborylative Cyanation. Angewandte Chemie (International ed. in English) 2024, e202408745. doi:10.1002/anie.202408745
  • Bennett, S. H.; Bestwick, J. S.; Demertzidou, V. P.; Jones, D. J.; Jones, H. E.; Richard, F.; Homer, J. A.; Street-Jeakings, R.; Tiberia, A. F.; Lawrence, A. L. Stereoretentive enantioconvergent reactions. Nature chemistry 2024, 16, 1177–1183. doi:10.1038/s41557-024-01504-1
  • Li, R.; Hu, Z.; Shuai, Z.; Yang, X. Catalytic Enantioconvergent C(sp3)−N Coupling to Access Chiral Amines: A Concept Review. ChemCatChem 2024, 16. doi:10.1002/cctc.202400049
  • Han, J.; Liu, X.; Jin, H.; Guo, P.; Xu, L.; Li, P.; Zhan, M. Iridium-catalyzed doubly stereoconvergent allylic alkylation of racemic α-boryl organozinc reagents. Chem Catalysis 2024, 4, 100858. doi:10.1016/j.checat.2023.100858
  • Carrillo-Cabrera, W.; Simon, P.; Schmidt, M.; König, M.; Borrmann, H.; Winkelmann, A.; Burkhardt, U.; Grin, Y. Enantiomorph conversion in single crystals of the Weyl semimetal CoSi. Communications Materials 2023, 4. doi:10.1038/s43246-023-00434-8
  • Mao, R.; Taylor, D. M.; Wackelin, D. J.; Wu, S. J.; Sicinski, K. M.; Arnold, F. H. Biocatalytic, Stereoconvergent Alkylation of (Z/E)-Trisubstituted Silyl Enol Ethers. Nature synthesis 2023, 3, 256–264. doi:10.1038/s44160-023-00431-2
  • Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium‐Catalyzed Asymmetric Synthesis of 1,2‐Disubstituted Allylic Fluorides. Angewandte Chemie 2023, 135. doi:10.1002/ange.202314843
  • Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium-Catalyzed Asymmetric Synthesis of 1,2-Disubstituted Allylic Fluorides. Angewandte Chemie (International ed. in English) 2023, 62, e202314843. doi:10.1002/anie.202314843
  • Yus, M.; Nájera, C.; Foubelo, F.; Sansano, J. M. Metal-Catalyzed Enantioconvergent Transformations. Chemical reviews 2023, 123, 11817–11893. doi:10.1021/acs.chemrev.3c00059
  • Ričko, S.; Bitsch, R. S.; Kaasik, M.; Otevřel, J.; Højgaard Madsen, M.; Keimer, A.; Jørgensen, K. A. Enantioconvergent 6π Electrocyclization Enabled by Photoredox Racemization. Journal of the American Chemical Society 2023, 145, 20913–20926. doi:10.1021/jacs.3c06227
  • Arachchi, M. K.; Schaugaard, R. N.; Schlegel, H. B.; Nguyen, H. M. Scope and Mechanistic Probe into Asymmetric Synthesis of α-Trisubstituted-α-Tertiary Amines by Rhodium Catalysis. Journal of the American Chemical Society 2023, 145, 19642–19654. doi:10.1021/jacs.3c04211
  • Sun, T.; Zhang, Z.; Su, Y.; Cao, H.; Zhou, Y.; Luo, G.; Cao, Z.-C. Nickel-Catalyzed Enantioconvergent Transformation of Anisole Derivatives via Cleavage of C-OMe Bond. Journal of the American Chemical Society 2023, 145, 15721–15728. doi:10.1021/jacs.3c05845
  • Zhou, B.; Ye, C.; Meggers, E. N‐Boc‐Protected α‐Amino Acids by 1,3‐Migratory Nitrene C(sp3)−H Insertion. European Journal of Organic Chemistry 2023, 26. doi:10.1002/ejoc.202300296
  • Cui, T.; Ye, C.; Thelemann, J.; Jenisch, D.; Meggers, E. Enantioselective and Enantioconvergent Iron‐Catalyzed C(sp3)‐H Aminations to Chiral 2‐Imidazolidinones. Chinese Journal of Chemistry 2023, 41, 2065–2070. doi:10.1002/cjoc.202300162
  • Ozawa, Y. Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitution of Racemic Allyl Electrophiles. Springer Theses; Springer Nature Singapore, 2023; pp 19–112. doi:10.1007/978-981-99-1098-4_2
  • Mao, R.; Wackelin, D. J.; Jamieson, C. S.; Rogge, T.; Gao, S.; Das, A.; Taylor, D. M.; Houk, K. N.; Arnold, F. H. Enantio- and Diastereoenriched Enzymatic Synthesis of 1,2,3-Polysubstituted Cyclopropanes from (Z/E)-Trisubstituted Enol Acetates. 2023. doi:10.21203/rs.3.rs-2802333/v1
  • Yang, J.; Massaro, L.; Hu, W.; Peters, B. B. C.; Birke, N.; Chantana, C.; Singh, T.; Andersson, P. G. Iridium-Catalyzed Double Convergent 1,3-Rearrangement/Hydrogenation of Allylic Alcohols. Journal of the American Chemical Society 2022, 145, 626–633. doi:10.1021/jacs.2c11289
Other Beilstein-Institut Open Science Activities