Enantioselective carbenoid insertion into C(sp³)–H bonds

Scholarly Works

• Li, X.; Yue, S.-H.; Tan, Z.-Y.; Liu, S.-B.; Luo, D.-X.; Zhou, Y.-J.; Liang, X.-W. Catalytic asymmetric carbenoid α-C-H insertion of ether. RSC advances 2024, 14, 15167–15177. doi:10.1039/d4ra02206h
• Wackelin, D. J.; Mao, R.; Sicinski, K. M.; Zhao, Y.; Das, A.; Chen, K.; Arnold, F. H. Enzymatic Assembly of Diverse Lactone Structures: An Intramolecular C-H Functionalization Strategy. Journal of the American Chemical Society 2024, 146, 1580–1587. doi:10.1021/jacs.3c11722
• Ghosh, T. Asymmetric Nickel-Catalyzed Reactions. Comprehensive Chirality; Elsevier, 2024; pp 234–353. doi:10.1016/b978-0-32-390644-9.00118-9
• Yan, M.; Xiao, L.; Xiong, J.; Jin, L.; Stephan, D. W.; Guo, J. Borane catalyzed transesterification of tert-butyl esters using α-aryl α-diazoesters. Organic & biomolecular chemistry 2023, 21, 8279–8283. doi:10.1039/d3ob01548c
• Santiago, J. V.; Orłowska, K.; Ociepa, M.; Gryko, D. Aryl versus Alkyl Redox-Active Diazoacetates ─ Light-Induced C-H Insertion or 1,2-Rearrangement. Organic letters 2023, 25, 6267–6271. doi:10.1021/acs.orglett.3c02055
• Sen, S.; Maiti, D.; Singh, S.; Gremaud, L. A Combination of Computational and Experimental Studies to Correlate Electronic Structure and Reactivity of Donor–Acceptor Singlet Carbenes. Synlett 2023, 35, 319–324. doi:10.1055/a-2153-6819
• Melen, R. L.; Pramanik, M. Activation of Diazo Compounds by Fluorinated Triarylborane Catalysts. Synthesis 2023, 55, 3906–3918. doi:10.1055/a-2118-3046
• Xiao, L.; Jin, L.; Zhao, Y.; Guo, J.; Stephan, D. W. B(C6F5)3-catalyzed cyclopropanation of 3-alkenyl-oxindoles with diazomethanes. Chemical communications (Cambridge, England) 2023, 59, 1833–1836. doi:10.1039/d2cc06744g
• Shibata, T.; Pan, S. doi:10.1002/9783527834242.chf0128
• Zhu, S.; Qin, J.; Huo, L.; Zhang, Y.; Chu, L. doi:10.1002/9783527834242.chf0204
• Han, F.; Choi, P. H.; Ye, C.-X.; Grell, Y.; Xie, X.; Ivlev, S. I.; Chen, S.; Meggers, E. Cyclometalated Chiral-at-Ruthenium Catalyst for Enantioselective Ring-Closing C(sp3)–H Carbene Insertion to Access Chiral Flavanones. ACS Catalysis 2022, 12, 10304–10312. doi:10.1021/acscatal.2c02423
• Wang, P.; Gong, Y.; Wang, X.; Ren, Y.; Wang, L.; Zhai, L.; Li, H.; She, X. Solvent-free, B(C6 F5 )3 -Catalyzed S-H Insertion of Thiophenols and Thiols with α-Diazoesters. Chemistry, an Asian journal 2022, 17, e202200465. doi:10.1002/asia.202200465
• Li, N.; Yang, X.; Zhu, Y.; Wang, F.; Gong, J.-F.; Song, M.-P. Pincer iridium(III)-catalyzed enantioselective C(sp3)-H functionalization via carbenoid C-H insertion of 3-diazooxindoles with 1,4-cyclohexadiene. Chinese Chemical Letters 2022, 33, 2437–2441. doi:10.1016/j.cclet.2021.11.067
• Kim, D.-H.; Kim, H.-M.; Lim, J.-S.; Lee, H.-W.; Cho, C.-G. Asymmetric Divergent Total Syntheses of (+)-Decursivine and (+)- Serotobenine via Intramolecular Fischer Indole Synthesis. Organic letters 2022, 24, 2873–2877. doi:10.1021/acs.orglett.2c00848
• Athavale, S. V.; Chen, K.; Arnold, F. H. doi:10.1002/9783527829170.ch4
• Dasgupta, A.; Richards, E.; Melen, R. L. Triarylborane Catalyzed Carbene Transfer Reactions Using Diazo Precursors. ACS catalysis 2021, 12, 442–452. doi:10.1021/acscatal.1c04746
• Pal, K.; Volla, C. M. R. Catalytic Insertion Reactions of α-Imino Carbenoids. Chemical record (New York, N.Y.) 2021, 21, 4032–4058. doi:10.1002/tcr.202100238
• Sambiagio, C.; Maes, B. U. W. Remote CH Bond Functionalizations; Wiley, 2021; pp 343–382. doi:10.1002/9783527824137.ch12
• Babu, S. A.; Padmavathi, R.; Suwasia, S.; Dalal, A.; Bhattacharya, D.; Singh, P.; Tomar, R. Recent developments on the synthesis of functionalized carbohydrate/sugar derivatives involving the transition metal–catalyzed C–H activation/C–H functionalization. Studies in Natural Products Chemistry; Elsevier, 2021; Vol. 71, pp 311–399. doi:10.1016/b978-0-323-91095-8.00001-5
• Woźniak, Ł.; Tan, J.-F.; Nguyen, Q.-H.; du Vigné, A. M.; Smal, V.; Cao, Y.-X.; Cramer, N. Catalytic Enantioselective Functionalizations of C-H Bonds by Chiral Iridium Complexes. Chemical reviews 2020, 120, 10516–10543. doi:10.1021/acs.chemrev.0c00559

Explore citations to this article at