Molecular-level architectural design using benzothiadiazole-based polymers for photovoltaic applications

Vinila N. Viswanathan, Arun D. Rao, Upendra K. Pandey, Arul Varman Kesavan and Praveen C. Ramamurthy
Beilstein J. Org. Chem. 2017, 13, 863–873. https://doi.org/10.3762/bjoc.13.87

Supporting Information

Supporting Information File 1: Experimental details and characterization data.
Format: PDF Size: 753.7 KB Download

Cite the Following Article

Molecular-level architectural design using benzothiadiazole-based polymers for photovoltaic applications
Vinila N. Viswanathan, Arun D. Rao, Upendra K. Pandey, Arul Varman Kesavan and Praveen C. Ramamurthy
Beilstein J. Org. Chem. 2017, 13, 863–873. https://doi.org/10.3762/bjoc.13.87

How to Cite

Viswanathan, V. N.; Rao, A. D.; Pandey, U. K.; Kesavan, A. V.; Ramamurthy, P. C. Beilstein J. Org. Chem. 2017, 13, 863–873. doi:10.3762/bjoc.13.87

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 656.2 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Mohammed, Y. A.; Hone, F. G.; Mola, G. T.; Tegegne, N. A. Non‐Electron Withdrawing Unit Copolymerization to Enhance Photo‐Stability of Thiophene‐Based Organic Solar Cells. Energy Technology 2024. doi:10.1002/ente.202401316
  • Nakamura, M.; Kanetani, I.; Gon, M.; Tanaka, K. NIR-II Absorption/Fluorescence of D-A π-Conjugated Polymers Composed of Strong Electron Acceptors Based on Boron-Fused Azobenzene Complexes. Angewandte Chemie (International ed. in English) 2024, 63, e202404178. doi:10.1002/anie.202404178
  • Nakamura, M.; Kanetani, I.; Gon, M.; Tanaka, K. NIR‐II Absorption/Fluorescence of D–A π‐Conjugated Polymers Composed of Strong Electron Acceptors Based on Boron‐Fused Azobenzene Complexes. Angewandte Chemie 2024, 136. doi:10.1002/ange.202404178
  • Gebremariam, K. G.; Hone, F. G.; Dai, J.; Mola, G. T.; Mammo, W.; Tegegne, N. A. Effect of an ambient environment on light-induced degradation of organic solar cells based on a benzodithiophene–quinoxaline copolymer in air. New Journal of Chemistry 2023, 47, 13331–13341. doi:10.1039/d3nj01953e
  • Nakamura, M.; Gon, M.; Tanaka, K.; Chujo, Y. Solid-State Near-Infrared Emission of π-Conjugated Polymers Consisting of Boron Complexes with Vertically Projected Steric Substituents. Macromolecules 2023, 56, 2709–2718. doi:10.1021/acs.macromol.2c02578
  • Valkeneers, K.; Vandewal, K.; Maes, W. Benzothiadiazole-based push-pull copolymers – Balancing synthetic complexity against organic solar cell efficiency. Organic Electronics 2022, 111, 106667. doi:10.1016/j.orgel.2022.106667
  • Shaik, S.; Reddy Sirigireddy, R. M.; Godugu, K.; Vemula, V.; Kakarla, R. R.; Balaraman, E.; Nallagondu, C. G. R.; Aminabhavi, T. M. SiO2-supported HClO4 catalyzed synthesis of (Z)-thiazolylhydrazonoindolin-2-ones and their electrochemical properties. Chemosphere 2022, 309, 136667. doi:10.1016/j.chemosphere.2022.136667
  • Mukherjee, R.; Srivastava, P.; Singh, P.; Bhardwaj, S.; Saha, A.; Viswanathan, V. N.; Ramamurthy, P. C.; Avasthi, S. D-A-D Structured Polymer Interlayer for Higher Open-Circuit Voltage and Stability in MAPbI3 Perovskite Solar Cells. Journal of Electronic Materials 2022, 51, 6699–6706. doi:10.1007/s11664-022-09914-y
  • Viswanathan, V. N.; Kesavan, A. v.; Ramamurthy, P. C. Enhancement in the inherent photostability of small molecule-based BHJ device by molecular architecturing. Materials Science and Engineering: B 2022, 283, 115841. doi:10.1016/j.mseb.2022.115841
  • Nellissery Viswanathan, V.; C Ramamurthy, P.; K Varman, A. Enhancement in the Inherent Photostability of Small Molecule-Based Bhj Device by Molecular Architecturing. SSRN Electronic Journal 2022. doi:10.2139/ssrn.4017230
  • Nakamura, M.; Gon, M.; Natsuda, S.-i.; Tamai, Y.; Ohkita, H.; Tanaka, K.; Chujo, Y. Development of NIR Emissive Fully-Fused Bisboron Complexes with π-Conjugated Systems Including Multiple Azo Groups. Dalton transactions (Cambridge, England : 2003) 2021, 51, 74–84. doi:10.1039/d1dt03652a
  • Gon, M.; Wakabayashi, J.; Nakamura, M.; Tanaka, K.; Chujo, Y. Controlling Energy Gaps of π-Conjugated Polymers by Multi-Fluorinated Boron-Fused Azobenzene Acceptors for Highly Efficient Near-Infrared Emission. Chemistry, an Asian journal 2021, 16, 696–703. doi:10.1002/asia.202100037
  • González-Antonio, O.; Yépez, R.; Vázquez-Alvarado, M. M.; Flores-Pérez, B.; Farfán, N.; Amador-Bedolla, C.; Romero-Ávila, M.; Santillan, R. Assessing electronic properties of desymmetrized heterocyclic patterns: towards tuning small molecules for photovoltaic applications. MRS Advances 2020, 5, 3171–3184. doi:10.1557/adv.2020.434
  • González-Antonio, O.; Yépez, R.; Vázquez-Alvarado, M. M.; Flores-Pérez, B.; Farfán, N.; Amador-Bedolla, C.; Romero-Ávila, M.; Santillan, R. Correction to: Assessing Electronic Properties of Desymmetrized Heterocyclic Patterns: Towards Tuning Small Molecules for Photovoltaic Applications. MRS Advances 2020, 5, 3171–3184.
  • Brook, C. P.; Paul, G.; Viswanathan, V. N.; Satyanarayana, S. B.; Panidhara, K. M.; Larson, B. W.; Ferguson, A. J.; Pal, A. J.; Ramamurthy, P. C.; Strauss, S. H.; Boltalina, O. V.; Braunecker, W. A. Molecular insights into photostability of fluorinated organic photovoltaic blends: role of fullerene electron affinity and donor–acceptor miscibility. Sustainable Energy & Fuels 2020, 4, 5721–5731. doi:10.1039/d0se00971g
  • Ledesma-Juárez, A.; Rodríguez, M.; Güizado-Rodríguez, M.; Romero-Borja, D.; Garcias-Morales, C.; Maldonado, J.-L.; Barba, V. Synthesis by direct arylation reaction of photovoltaic D–π–A polymers based on fluorene-thiophene- fragment and fluorinated benzothiadiazole derivatives. Journal of Materials Science: Materials in Electronics 2019, 30, 13974–13983. doi:10.1007/s10854-019-01744-9
  • Tarafdar, G.; Pandey, U. K.; Sengupta, S.; Ramamurthy, P. C. Effect of structural isomerism in BODIPY based donor-acceptor co-polymers on their photovoltaic performance. Solar Energy 2019, 186, 215–224. doi:10.1016/j.solener.2019.04.093
  • Hamer, S.; Röhricht, F.; Jakoby, M.; Howard, I. A.; Zhang, X.; Näther, C.; Herges, R. Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks. Beilstein journal of organic chemistry 2019, 15, 1331–1338. doi:10.3762/bjoc.15.132
  • Taouali, W.; Casida, M. E.; Znaidia, S.; Alimi, K. Rational design of (D-A) copolymers towards high efficiency organic solar cells: DFT and TD-DFT study. Journal of molecular graphics & modelling 2019, 89, 139–146. doi:10.1016/j.jmgm.2019.03.014
  • Raychev, D.; Lopez, R.; Kiriy, A.; Seifert, G.; Sommer, J.-U.; Guskova, O. Copolymers of Diketopyrrolopyrrole and Benzothiadiazole: Design and Function from Simulations with Experimental Support. Macromolecules 2019, 52, 904–914. doi:10.1021/acs.macromol.8b02500
Other Beilstein-Institut Open Science Activities