Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethylsilane: a general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer

Scholarly Works

• Jankins, T. C.; Blank, P. M.; Brugnetti, A.; Boehm, P.; Aouane, F. A.; Morandi, B. Shuttle HAT for mild alkene transfer hydrofunctionalization. Nature communications 2024, 15, 9397. doi:10.1038/s41467-024-53281-7
• Zhang, Y.; Zhang, Y.; Xue, X.; Qing, F. Reversal of the Regioselectivity of Iron‐Promoted Hydrogenation and Hydrohalogenation of gem‐Difluoroalkenes. Angewandte Chemie 2024, 136. doi:10.1002/ange.202406324
• Zhang, Y.-Y.; Zhang, Y.; Xue, X.-S.; Qing, F.-L. Reversal of the Regioselectivity of Iron-Promoted Hydrogenation and Hydrohalogenation of gem-Difluoroalkenes. Angewandte Chemie (International ed. in English) 2024, 63, e202406324. doi:10.1002/anie.202406324
• Müller, D. S. Advancements in hydrochlorination of alkenes. Beilstein journal of organic chemistry 2024, 20, 787–814. doi:10.3762/bjoc.20.72
• Li, X.-R.; Zhang, R.-J.; Xiao, Y.; Tong, Q.-X.; Zhong, J.-J. N-Sulfenyl phthalimide enabled Markovnikov hydrothiolation of unactivated alkenes via ligand promoted cobalt catalysis. Organic Chemistry Frontiers 2024, 11, 646–653. doi:10.1039/d3qo01632c
• Zhang, R.-J.; Li, X.-R.; Liang, R.-B.; Xiao, Y.; Tong, Q.-X.; Zhong, J.-J.; Wu, L.-Z. Thiyl Radical Trapped by Cobalt Catalysis: An Approach to Markovnikov Thiol-Ene Reaction. Organic letters 2024, 26, 591–596. doi:10.1021/acs.orglett.3c03740
• Kourgiantaki, M.; Demertzidou, V. P.; Zografos, A. L. Short Scalable Route to Apiaceae Sesquiterpene Scaffolds: Total Synthesis of 4-epi-Epiguaidiol A. Organic letters 2022, 24, 8476–8480. doi:10.1021/acs.orglett.2c03215
• Ram Bajya, K.; Selvakumar, S. Dual Photoredox and Cobalt Catalysis Enabled Transformations. European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202200229
• Price, J. S.; Emslie, D. J. Cyclic and Non-Cyclic Pi Complexes of Manganese. Comprehensive Organometallic Chemistry IV; Elsevier, 2022; pp 378–546. doi:10.1016/b978-0-12-820206-7.00077-9
• Sun, F.; Suttapitugsakul, S.; Wu, R. An Azo Coupling-Based Chemoproteomic Approach to Systematically Profile the Tyrosine Reactivity in the Human Proteome. Analytical chemistry 2021, 93, 10334–10342. doi:10.1021/acs.analchem.1c01935
• Kattamuri, P. V.; West, J. G. Cooperative Hydrogen Atom Transfer: From Theory to Applications. Synlett 2021, 32, 1179–1186. doi:10.1055/a-1463-9527
• Kamei, Y.; Seino, Y.; Yamaguchi, Y.; Yoshino, T.; Maeda, S.; Kojima, M.; Matsunaga, S. Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis. Nature communications 2021, 12, 966. doi:10.1038/s41467-020-20872-z
• Yuki, Y.; Shin-ichi, K.; Shintaro, K.; Akihiro, N.; Akiya, O. Highly Selective Hydroiodination of Carbon-Carbon Double or Triple Bonds. Current Organic Chemistry 2020, 24, 2153–2168. doi:10.2174/1385272824666191227111257
• Kattamuri, P. V.; West, J. G. Hydrogenation of Alkenes via Cooperative Hydrogen Atom Transfer. Journal of the American Chemical Society 2020, 142, 19316–19326. doi:10.1021/jacs.0c09544
• Sun, H.-L.; Yang, F.; Ye, W.-T.; Wang, J.-J.; Zhu, R. Dual Cobalt and Photoredox Catalysis Enabled Intermolecular Oxidative Hydrofunctionalization. ACS Catalysis 2020, 10, 4983–4989. doi:10.1021/acscatal.0c01209
• Date, S.; Hamasaki, K.; Sunagawa, K.; Koyama, H.; Sebe, C.; Hiroya, K.; Shigehisa, H. Catalytic Direct Cyclization of Alkenyl Thioester. ACS Catalysis 2020, 10, 2039–2045. doi:10.1021/acscatal.9b05045
• Yasukawa, T.; Kobayashi, S. Oxygenation of Styrenes Catalyzed by N-Doped Carbon Incarcerated Cobalt Nanoparticles. Bulletin of the Chemical Society of Japan 2019, 92, 1980–1985. doi:10.1246/bcsj.20190251
• Krajewski, S. M.; Crossman, A. S.; Akturk, E. S.; Suhrbier, T.; Scappaticci, S. J.; Staab, M. W.; Marshak, M. P. Sterically encumbered β-diketonates and base metal catalysis. Dalton transactions (Cambridge, England : 2003) 2019, 48, 10714–10722. doi:10.1039/c9dt02293g
• Hori, H.; Arai, S.; Nishida, A. Cobalt-catalyzed cyclization with the introduction of cyano, acyl and aminoalkyl groups. Organic & biomolecular chemistry 2019, 17, 4783–4788. doi:10.1039/c9ob00637k
• Zhou, X.-L.; Yang, F.; Sun, H.-L.; Yin, Y.-N.; Ye, W.-T.; Zhu, R. Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway. Journal of the American Chemical Society 2019, 141, 7250–7255. doi:10.1021/jacs.9b01857

Explore citations to this article at