Recent advances in transition-metal-catalyzed incorporation of fluorine-containing groups

Scholarly Works

• Yamaguchi, M.; Shimao, H.; Hamasaki, K.; Nishiwaki, K.; Kashimura, S.; Matsumoto, K. gem-Difluorination of carbon-carbon triple bonds using Brønsted acid/Bu4NBF4 or electrogenerated acid. Beilstein journal of organic chemistry 2024, 20, 2261–2269. doi:10.3762/bjoc.20.194
• Peng, Y.; Ullah, S.; Hussain, Z. Recent Advances in Diazophosphonate Chemistry: Reactions and Transformations. Synthesis 2024. doi:10.1055/s-0040-1720129
• Han, J.; Zhang, Z. (Radio)Fluorination Reactions for the Synthesis of Aryl Fluorides: Recent Advances and Perspectives. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202400502
• Huang, J.; Liu, Y.; Tian, X.; Ni, S.-F.; Li, S.; Zhang, Z.-H.; Li, D.; Liu, S. Visible light-induced FeCl3-catalyzed chlorination of C–H bonds with MgCl2. Green Chemistry 2024, 26, 6559–6569. doi:10.1039/d4gc00664j
• Amistadi‐Revol, H.; Tremblais, J.; Casaretto, N.; Prévost, S. Palladium‐Catalyzed C8‐Fluoroalkylation and C8‐Fluoroalkenylation of Naphthalenes by C−H Activation. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202400194
• Casitas, A.; Andreetta, P. Iron-catalyzed group-transfer reactions with iodine(III) reagents. Advances in Catalysis; Elsevier, 2024; pp 33–99. doi:10.1016/bs.acat.2024.05.003
• Nobile, E.; Doche, F.; Castanheiro, T.; Musaev, D. G.; Besset, T. Copper-Catalyzed C-H (Phenylsulfonyl)difluoromethylation of Acrylamides: Scope, Mechanism, and Critical Role of Additives. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202303362. doi:10.1002/chem.202303362
• Joseph, E.; Smith, I.; Tunge, J. A. Cobalt-catalyzed decarboxylative difluoroalkylation of nitrophenylacetic acid salts. Chemical science 2023, 14, 13902–13907. doi:10.1039/d3sc05583c
• Marçal, G. C.; Pliego, J. R. Trifluoromethyl anion: Generation, stability, and SNAr reactivity in crown ether complex analyzed by theoretical calculations. Computational and Theoretical Chemistry 2023, 1230, 114360. doi:10.1016/j.comptc.2023.114360
• Cho, H.; Jang, S.; Lee, K.; Cha, D.; Min, S.-J. Visible-Light-Induced DDQ-Catalyzed Fluorocarbamoylation Using CF3SO2Na and Oxygen. Organic letters 2023, 25, 8558–8563. doi:10.1021/acs.orglett.3c03335
• Alayoglu, P.; Chang, T.; Yan, C.; Chen, Y.; Mankad, N. P. Uncovering a CF3 Effect on X‐ray Absorption Energies of [Cu(CF3)4]− and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements**. Angewandte Chemie 2023, 135. doi:10.1002/ange.202313744
• Alayoglu, P.; Chang, T.; Yan, C.; Chen, Y.-S.; Mankad, N. P. Uncovering a CF3 Effect on X-ray Absorption Energies of [Cu(CF3 )4 ]- and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements. Angewandte Chemie (International ed. in English) 2023, 62, e202313744. doi:10.1002/anie.202313744
• Gao, Y.; Xiao, R.; Zhang, S.; Wang, Y.; Yuan, Z. Direct Trifluoromethylselenolation and Fluoroalkylselenolation of C−H Bonds: Recent Advances in Reagents Development and Reactions. European Journal of Organic Chemistry 2023, 26. doi:10.1002/ejoc.202300668
• Yuan, Z.-H.; Xin, H.; Zhang, L.; Gao, P.; Yang, X.; Duan, X.-H.; Guo, L.-N. Metal-free, visible-light driven α-C(sp3)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1,3-enynes. Green Chemistry 2023, 25, 6733–6738. doi:10.1039/d3gc01750h
• Sumii, Y.; Shibata, N. Current State of Microflow Trifluoromethylation Reactions. Chemical record (New York, N.Y.) 2023, 23, e202300117. doi:10.1002/tcr.202300117
• Li, Y.; Lu, D.; Gong, Y. Cu-catalysed three-component C–H trifluoroalkylation of glycine derivatives: access to diverse CF3-containing amino acids. Organic Chemistry Frontiers 2023, 10, 2301–2309. doi:10.1039/d3qo00267e
• Monsigny, L.; Doche, F.; Besset, T. Transition-metal-catalyzed C-H bond activation as a sustainable strategy for the synthesis of fluorinated molecules: an overview. Beilstein journal of organic chemistry 2023, 19, 448–473. doi:10.3762/bjoc.19.35
• Kuninobu, Y. Regioselective C-H Trifluoromethylation and Its Related Reactions of (Hetero)aromatic Compounds. Chemical record (New York, N.Y.) 2023, 23, e202300003. doi:10.1002/tcr.202300003
• Kalar, P. L.; Agrawal, S.; Kushwaha, S.; Gayen, S.; Das, K. Recent Developments on Synthesis of Organofluorine Compounds Using Green Approaches. Current Organic Chemistry 2023, 27, 190–205. doi:10.2174/1385272827666230516100739
• Brezová, V.; Barbieriková, Z.; Zalibera, M.; Lušpai, K.; Tholtová, A.; Dvoranová, D. Titania-mediated photoinduced fluorination of nitrone spin traps in acetonitrile (an EPR study). Journal of Photochemistry and Photobiology A: Chemistry 2022, 432, 114111. doi:10.1016/j.jphotochem.2022.114111

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