Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow

Scholarly Works

• Chen, M.; Lu, Y.; Shen, Y.; Wang, Q. N-Trifluoroethoxy Benzotriazolium Triflate: A Readily Available Reagent for Direct Radical Trifluoroethoxylation of Alkenes. Organic letters 2024, 26, 9586–9591. doi:10.1021/acs.orglett.4c03710
• Boronin, E. N.; Svetlakova, M. M.; Vorobyov, I. I.; Malysheva, Y. B.; Polushtaytsev, Y. V.; Mensov, S. N.; Vorotyntsev, A. V.; Fedorov, A. Y.; Noël, T.; Nyuchev, A. V. Photochemical organocatalytic heteroarylation of anilines and secondary alicyclic amines in continuous-flow. Reaction Chemistry & Engineering 2024, 9, 1877–1882. doi:10.1039/d4re00130c
• Fernandes, A. J.; Giri, R.; Houk, K. N.; Katayev, D. Review and Theoretical Analysis of Fluorinated Radicals in Direct CAr−H Functionalization of (Hetero)arenes. Angewandte Chemie 2024, 136. doi:10.1002/ange.202318377
• Fernandes, A. J.; Giri, R.; Houk, K. N.; Katayev, D. Review and Theoretical Analysis of Fluorinated Radicals in Direct CAr-H Functionalization of (Hetero)arenes. Angewandte Chemie (International ed. in English) 2024, 63, e202318377. doi:10.1002/anie.202318377
• Maas, L. M.; Fasting, C.; Voßnacker, P.; Limberg, N.; Golz, P.; Müller, C.; Riedel, S.; Hopkinson, M. N. Catalyst-Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide. Angewandte Chemie (International ed. in English) 2024, 63, e202317770. doi:10.1002/anie.202317770
• Maas, L. M.; Fasting, C.; Voßnacker, P.; Limberg, N.; Golz, P.; Müller, C.; Riedel, S.; Hopkinson, M. N. Catalyst‐Free Trifluoromethoxylation of Silyl Enol Ethers and Allyl Silanes with Bis(trifluoromethyl)peroxide. Angewandte Chemie 2024, 136. doi:10.1002/ange.202317770
• Xu, Y.; Zhao, F.; Guo, X. Continuous microflow visible-light photocatalytic N-formylation of piperidine and its kinetic study. Chinese Chemical Letters 2024, 35, 108642. doi:10.1016/j.cclet.2023.108642
• Hao, B.-Y.; Han, Y.-P.; Zhang, Y.; Liang, Y.-M. New synthetic approaches toward OCF3-containing compounds. Organic & biomolecular chemistry 2023, 21, 4926–4954. doi:10.1039/d3ob00258f
• Si, Y.; Tang, P. Development and Application of Trifluoromethoxylating Reagents. Chinese Journal of Chemistry 2023, 41, 2179–2196. doi:10.1002/cjoc.202300093
• Bellotti, P.; Huang, H.-M.; Faber, T.; Glorius, F. Photocatalytic Late-Stage C-H Functionalization. Chemical reviews 2023, 123, 4237–4352. doi:10.1021/acs.chemrev.2c00478
• Pieber, B. doi:10.1002/9783527834242.chf0152
• Roider, T.; Frommknecht, N.; Höltzel, A.; Tallarek, U. Device for automated screening of irradiation wavelength and intensity – investigation of the wavelength dependence of photoreactions with an arylazo sulfone in continuous flow. Reaction Chemistry & Engineering 2022, 7, 2035–2044. doi:10.1039/d2re00142j
• Barata-Vallejo, S.; Bonesi, S. M.; Postigo, A. Trifluoromethoxylation Reactions of (Hetero) arenes, Olefinic Systems and Aliphatic Saturated Substrates. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202201776. doi:10.1002/chem.202201776
• Dong, Z.; Zondag, S. D. A.; Schmid, M.; Wen, Z.; Noël, T. A meso-scale ultrasonic milli-reactor enables gas–liquid-solid photocatalytic reactions in flow. Chemical Engineering Journal 2022, 428, 130968. doi:10.1016/j.cej.2021.130968
• Chang, L.; An, Q.; Duan, L.; Feng, K.; Zuo, Z. Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis. Chemical reviews 2021, 122, 2429–2486. doi:10.1021/acs.chemrev.1c00256
• Candish, L.; Collins, K. D.; Cook, G. C.; Douglas, J.; Gómez-Suárez, A.; Jolit, A.; Keess, S. Photocatalysis in the Life Science Industry. Chemical reviews 2021, 122, 2907–2980. doi:10.1021/acs.chemrev.1c00416
• Duhail, T.; Bortolato, T.; Mateos, J.; Anselmi, E.; Jelier, B. J.; Togni, A.; Magnier, E.; Dagousset, G.; Dell'Amico, L. Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis. Organic letters 2021, 23, 7088–7093. doi:10.1021/acs.orglett.1c02494
• Buglioni, L.; Raymenants, F.; Slattery, A.; Zondag, S. D. A.; Noël, T. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry. Chemical reviews 2021, 122, 2752–2906. doi:10.1021/acs.chemrev.1c00332
• Dix, S.; Golz, P.; Schmid, J. R.; Riedel, S.; Hopkinson, M. N. Radical C−H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide. Chemistry (Weinheim an der Bergstrasse, Germany) 2021, 27, 11554–11558. doi:10.1002/chem.202101621
• Wang, F.; Guo, Y.; Zhang, Y.; Tang, P. Silver-Catalyzed Dibromotrifluoromethoxylation of Terminal Alkynes. ACS Catalysis 2021, 11, 3218–3223. doi:10.1021/acscatal.1c00090

Explore citations to this article at