All-carbon [3 + 2] cycloaddition in natural product synthesis

Scholarly Works

• Alves, A. J. S.; Silvestre, J. A. D.; Pinho e Melo, T. M. V. D. Continuous Flow Spirocyclization Reactions: Towards Efficient Synthesis of Chiral Spiropenicillanates. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202400689
• Song, J.-Y.; Sun, X.-Y.; Wang, B.-L.; Zhou, S.-S.; Song, J.-X.; Zhang, B.-H.; Wang, X.-W. COAP-Pd Catalyzed Asymmetric Formal [3+2] Cycloaddition for Optically Active Multistereogenic Spiro Cyclopentane-Indandiones Bearing Cyclic N-Sulfonyl Ketimine Skeletons. Chemistry, an Asian journal 2024, 19, e202400184. doi:10.1002/asia.202400184
• Qatran Al-Khdhairawi, A. A.; Yuan, T.; Van Hecke, K.; Winne, J. M. Dearomative (3 + 2) Cycloaddition of Indoles for the Stereoselective Assembly of Fully Functionalized Cyclopentanoids. Organic letters 2024, 26, 4077–4081. doi:10.1021/acs.orglett.4c01139
• Ishihara, J. Progress in Lewis-Acid-Templated Diels-Alder Reactions. Molecules (Basel, Switzerland) 2024, 29, 1187. doi:10.3390/molecules29051187
• Gupta, K.; Harariya, M. S.; Tyagi, A.; Jindal, G. Overview of Transition Metal Catalyzed Multicomponent Reactions Based on Trapping of Allylic Electrophiles. ChemCatChem 2024, 16. doi:10.1002/cctc.202301215
• Dhandabani, G. K.; Jeyakannu, P.; Shih, C.-L.; Abraham, A. M.; Senadi, G. C.; Wang, J.-J. A Regioselective [3 + 2] Cycloaddition of Alkynols and Ketones To Access Diverse 1,3-Dioxolane Scaffolds. The Journal of organic chemistry 2023, 89, 719–724. doi:10.1021/acs.joc.3c01820
• Kowalska, E.; Dyguda, M.; Artelska, A.; Albrecht, A. Visible Light Promoted [3+2]-Cycloaddition for the Synthesis of Cyclopenta[b]chromenocarbonitrile Derivatives. The Journal of organic chemistry 2023, 88, 16589–16597. doi:10.1021/acs.joc.3c02172
• Degroote, F.; Denoo, B.; Ryckaert, B.; Callebaut, B.; Van Hecke, K.; Hullaert, J.; Winne, J. M. Dithioallyl cation (3 + 2) cycloadditions under aprotic reaction conditions: rapid access to spiro-fused cyclopentane scaffolds. Organic & biomolecular chemistry 2023, 21, 8117–8124. doi:10.1039/d3ob01273e
• Wu, W.-Q.; Lin, Y.; Li, Y.; Shi, H. Catalytic Dehydrogenative (3 + 2) Cycloaddition of Alkylbenzenes via π-Coordination. Journal of the American Chemical Society 2023, 145, 9464–9470. doi:10.1021/jacs.3c02900
• Mao, Y.; Fan, P.; Wang, C. Photocatalyzed Formal All-Carbon [3+2] Cycloaddition of Aromatic Aldehydes with Arylethynyl Silanes. Organic letters 2022, 24, 9413–9418. doi:10.1021/acs.orglett.2c03807
• Deepthi, A.; Mohan, M.; Balachandran, M. C. Recent Progress on the [3+2] Cycloaddition Route for the Synthesis of All-Carbon Quaternary Stereocentres. SynOpen 2022, 6, 270–285. doi:10.1055/a-1947-3351
• Hui, C.; Wang, S.; Xu, C. Dinitrogen extrusion from diazene in organic synthesis. Chinese Chemical Letters 2022, 33, 3695–3700. doi:10.1016/j.cclet.2022.03.073
• Ryckaert, B.; Hullaert, J.; Van Hecke, K.; Winne, J. M. Dearomative (3 + 2) Cycloadditions of Unprotected Indoles. Organic letters 2022, 24, 4119–4123. doi:10.1021/acs.orglett.2c01214
• Niedbała, P.; Majdecki, M.; Grodek, P.; Jurczak, J. H-Bond Mediated Phase-Transfer Catalysis: Enantioselective Generating of Quaternary Stereogenic Centers in β-Keto Esters. Molecules (Basel, Switzerland) 2022, 27, 2508. doi:10.3390/molecules27082508
• Luque, A.; Groß, J.; Zähringer, T. J. B.; Kerzig, C.; Opatz, T. Vinylcyclopropane [3+2] Cycloaddition with Acetylenic Sulfones Based on Visible Light Photocatalysis. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202104329. doi:10.1002/chem.202104329
• Luque, A.; Groß, J.; Opatz, T. Vinylcyclopropane [3+2] Cycloaddition with Acetylenic Sulfones Based on Visible Light Photocatalysis. Cambridge University Press (CUP) 2021. doi:10.33774/chemrxiv-2021-k7k1w
• Mousavi, H. A comprehensive survey upon diverse and prolific applications of chitosan-based catalytic systems in one-pot multi-component synthesis of heterocyclic rings. International journal of biological macromolecules 2021, 186, 1003–1166. doi:10.1016/j.ijbiomac.2021.06.123
• Tran, D. P.; Sato, Y.; Yamamoto, Y.; Kawaguchi, S.; Kodama, S.; Nomoto, A.; Ogawa, A. Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions. Beilstein journal of organic chemistry 2021, 17, 866–872. doi:10.3762/bjoc.17.72

Explore citations to this article at