Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate

Scholarly Works

• Gao, G.; Xie, K.; Shi, M.; Gao, T.; Wang, Z.; Zhang, C.; Wang, Z. Direct trifluoromethylselenolations of electron-rich (hetero)aromatic rings with N-trifluoromethylselenolating saccharin. Organic & biomolecular chemistry 2024, 22, 7707–7714. doi:10.1039/d4ob01134a
• Bagnoli, L.; Rosati, O.; Marini, F.; Santi, C.; Sancineto, L. Selenosulfones, a Meetup of Chalcogens: A Journey Into Their Recent Chemistry. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202400169
• Gao, Y.; Xiao, R.; Feng, B.; Bian, Z.; Zhang, H.; Zhu, G.; Wang, Y.; Yuan, Z. Metal-free Lewis-acid-catalyzed divergent trifluoromethylselenolation of alkynes: construction of α-trifluoromethylselenolated ketones and alkynes. Organic Chemistry Frontiers 2023, 10, 4905–4911. doi:10.1039/d3qo01111a
• Wang, Z.; Hu, J.; Liu, W.; Chen, C. Dehydroxytrifluoromethylthiolation(selenolation) of alcohols with C S(Se)CF3 reagent based on imidazole skeleton. Tetrahedron Letters 2023, 127, 154670. doi:10.1016/j.tetlet.2023.154670
• Weiss, R.; Aubert, E.; Groslambert, L.; Pale, P.; Mamane, V. Evidence for and evaluation of fluorine-tellurium chalcogen bonding. Chemical science 2023, 14, 7221–7229. doi:10.1039/d3sc00849e
• Hu, Z.; Wu, J.; Wu, J.; Wu, F. Research Progress on Direct Trifluoromethylselenylation. Chinese Journal of Organic Chemistry 2023, 43, 36. doi:10.6023/cjoc202206050
• Krykun, S.; Durandetti, M. Nickel‐Catalyzed Electrochemical Synthesis of (Hetero)Aryl Trifluoromethyl Selenides. European Journal of Organic Chemistry 2022, 26. doi:10.1002/ejoc.202201393
• Wegener, D.; Hoffmann, K. F.; Pérez-Bitrián, A.; Bayindir, I.; Hadi, A. N.; Wiesner, A.; Riedel, S. Air-stable aryl derivatives of pentafluoroorthotellurate. Chemical communications (Cambridge, England) 2022, 58, 9694–9697. doi:10.1039/d2cc03936b
• Grollier, K.; Ghiazza, C.; Tlili, A.; Billard, T.; Médebielle, M.; Vantourout, J. C. Electrochemical Trifluoromethylselenolation of Activated Alkyl Halides. European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202200123
• Grollier, K.; Chefdeville, E.; De Zordo-Banliat, A.; Pégot, B.; Dagousset, G.; Magnier, E.; Billard, T. Fe-mediated nucleophilic trifluoromethylselenolation of activated alkyl bromides via umpolung reactivity of trifluoromethyl tolueneselenosulfinate. Tetrahedron 2021, 100, 132498. doi:10.1016/j.tet.2021.132498
• Wang, H.-N.; Dong, J.-Y.; Shi, J.; Zhang, C.-P. Trifluoromethylselenolation reactions using the versatile [Me4N][SeCF3] reagent. Tetrahedron 2021, 99, 132476. doi:10.1016/j.tet.2021.132476
• Ghiazza, C.; Billard, T. Synthesis, Reactivity and Activation Modes of Fluoroalkyl Thiosulfonates and Selenosulfonates. European Journal of Organic Chemistry 2021, 2021, 5571–5584. doi:10.1002/ejoc.202100944
• Wang, Y.; Ye, Z.; Zhang, H.; Yuan, Z. Recent Advances in the Development of Direct Trifluoromethylselenolation Reagents and Methods. Advanced Synthesis & Catalysis 2021, 363, 1835–1854. doi:10.1002/adsc.202001508

Explore citations to this article at