Synthesis of organic liquid crystals containing selectively fluorinated cyclopropanes

Scholarly Works

• Freitas, M. P. Thermodynamics and polarity-driven properties of fluorinated cyclopropanes. Beilstein journal of organic chemistry 2025, 21, 1742–1747. doi:10.3762/bjoc.21.137
• Li, S.-Y.; Yuan, S.; Zhao, X.-M.; Wang, Q.; Zhu, J.; Zheng, S.-C. Highly diastereoselective and enantioselective cyclopropanation of alkenes catalyzed by a chiral iridium(III) porphyrin complex. Chem Catalysis 2025, 5, 101262. doi:10.1016/j.checat.2024.101262
• Mishra, M.; Kumar, M.; Singh, D.; Thapa, K. B.; Pandey, G.; Kumar, D. DFT study of difluoro & trifluoro bi-cyclohexane based dimer for application in electronic and optical devices. Journal of Molecular Liquids 2024, 414, 126109. doi:10.1016/j.molliq.2024.126109
• Mo, L.; Wan, D.; Li, J.; Che, Z.; Hu, M.; An, Z.; Li, J. Synthesis and properties of dibenzofuran- and dibenzothiophene-based mesogens: An effective access to liquid crystals with large negative dielectric anisotropy. Journal of Molecular Liquids 2024, 405, 125061. doi:10.1016/j.molliq.2024.125061
• Zeng, X.; Yang, J.; Deng, W.; Feng, X.-T.; Zhao, H.-Y.; Wei, L.; Xue, X.-S.; Zhang, X. Copper Difluorocarbene Enables Catalytic Difluoromethylation. Journal of the American Chemical Society 2024, 146, 16902–16911. doi:10.1021/jacs.4c04949
• Zhang, X.-Y.; Sun, S.-P.; Sang, Y.-Q.; Xue, X.-S.; Min, Q.-Q.; Zhang, X. Reductive Catalytic Difluorocarbene Transfer via Palladium Catalysis. Angewandte Chemie (International ed. in English) 2023, 62, e202306501. doi:10.1002/anie.202306501
• Zhang, X.; Sun, S.; Sang, Y.; Xue, X.; Min, Q.; Zhang, X. Reductive Catalytic Difluorocarbene Transfer via Palladium Catalysis. Angewandte Chemie 2023, 135. doi:10.1002/ange.202306501
• Wan, D.; Wu, Y.; Mo, L.; Che, Z.; Li, J.; Hu, M.; Liang, L.; An, Z.; Li, J. Increasing the negative dielectric anisotropy of liquid crystals with polar substituents parallel to their long molecular axis through adding terminal 2,2-difluoroethyl group. Liquid Crystals 2023, 50, 2176–2185. doi:10.1080/02678292.2023.2238659
• O'Hagan, D. The Emergence and Properties of Selectively Fluorinated 'Janus' Cyclohexanes. Chemical record (New York, N.Y.) 2023, 23, e202300027. doi:10.1002/tcr.202300027
• Itoh, T.; Hayase, S.; Nokami, T. Synthesis of Selectively gem-Difluorinated Molecules; Chiral gem-Difluorocyclopropanes via Chemo-Enzymatic Reaction and gem-Difluorinated Compounds via Radical Reaction. Chemical record (New York, N.Y.) 2023, 23, e202300028. doi:10.1002/tcr.202300028
• Clark, J.; Taylor, A.; Geddis, A.; Neyyappadath, R. M.; Piscelli, B.; Yu, C.; Cordes, D. B.; Slawin, A. M. Z.; Cormanich, R. A.; Guldin, S.; O'Hagan, D. Supramolecular packing of alkyl substituted Janus face all-cis 2,3,4,5,6-pentafluorocyclohexyl motifs. Chemical science 2021, 12, 9712–9719. doi:10.1039/d1sc02130c
• Mondal, R.; Agbaria, M.; Nairoukh, Z. Fluorinated Rings: Conformation and Application. Chemistry (Weinheim an der Bergstrasse, Germany) 2021, 27, 7193–7213. doi:10.1002/chem.202005425
• Adekenova, K. S.; Wyatt, P. B.; Adekenov, S. M. The preparation and properties of 1,1-difluorocyclopropane derivatives. Beilstein journal of organic chemistry 2021, 17, 245–272. doi:10.3762/bjoc.17.25
• Decaens, J.; Couve-Bonnaire, S.; Charette, A. B.; Poisson, T.; Jubault, P. Synthesis of Fluoro-, Monofluoromethyl-, Difluoromethyl-, and Trifluoromethyl-Substituted Three-Membered Rings. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 27, 2935–2962. doi:10.1002/chem.202003822

Explore citations to this article at