Correction: Amine–borane complex-initiated SF5Cl radical addition on alkenes and alkynes

Audrey Gilbert; Pauline Langowski; Marine Delgado; Laurent Chabaud; Mathieu Pucheault; Jean-François Paquin

doi:10.3762/bjoc.17.120

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Correction: Amine–borane complex-initiated SF₅Cl radical addition on alkenes and alkynes

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¹Départment de chimie, Université Laval, Québec, QC, G1V 0A6, Canada

²Institut des Sciences Moléculaires - Groupe ORGA - UMR 5255, Université de Bordeaux, 351 Cours de la libération, 33405 Talence, France

Corresponding author email

Guest Editor: D. O'Hagan
Beilstein J. Org. Chem. 2021, 17, 1725–1726. https://doi.org/10.3762/bjoc.17.120
Received 08 Jul 2021, Accepted 16 Jul 2021, Published 23 Jul 2021

Correction

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This correction refers to Beilstein J. Org. Chem. 2020, 16, 3069–3077. doi:10.3762/bjoc.16.256

Keywords: amine–borane complex; pentafluorosulfanyl chloride; pentafluorosulfanyl substituent; radical addition; radical initiation

The stereochemistry of some alkene products (2i–k) in Scheme 4 of the original publication was misattributed. The corrected structures are shown in Scheme 1.

[1860-5397-17-120-i1] — **Scheme 1:** Corrected Scheme 4 of the original article. Scope of the Et₃B and the DICAB-initiated SF₅Cl additions on alkynes. Unless noted otherwise, isolated yields are reported. ^aYield estimated by ¹⁹F NMR analysis of the crude mixture using 2-fluoro-4-nitrotoluene as an internal standard.

**Scheme 1:** Corrected Scheme 4 of the original article. Scope of the Et₃B and the DICAB-initiated SF₅Cl additio...

Jump to Scheme 1

A corrected version of Supporting Information File 1 is also part of this Correction. The new Supporting Information File 1 is the complete file with the corrections marked in yellow color.

Finally, the Table of Content graphic was also corrected. The corrected version of the original graphical abstract is shown in Scheme 2.

[1860-5397-17-120-i2] — **Scheme 2:** Corrected graphical abstract of the original publication.

**Scheme 2:** Corrected graphical abstract of the original publication.

Jump to Scheme 2

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Supporting Information

Supporting Information File 1: General information, synthetic procedures, additional optimization results, NMR spectra for known compounds (¹H, ¹⁹F) and full characterization of all new compounds.
Format: PDF	Size: 2.6 MB	Download

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