Synthetic reactions driven by electron-donor–acceptor (EDA) complexes

Scholarly Works

• Hanumanthu, R.; Sharma, P.; Ethridge, A.; Weaver, J. D. Co-Catalytic Coupling of Alkyl Halides and Alkenes: the Curious Role of Lutidine. Journal of the American Chemical Society 2025, 147, 5238–5246. doi:10.1021/jacs.4c15812
• Luo, X.; Lou, S.-J.; Sun, Y.-B.; Jing, C.-C.; Fei, X.; Zhang, X.-X.; Zhai, J.-J.; Wang, Y.-F.; Xu, D.-Q. Practical heptafluoroisopropylation of nitrogen-containing (hetero)aromatics under visible light. Organic Chemistry Frontiers 2025, 12, 800–807. doi:10.1039/d4qo01660b
• Wang, S.; Wang, L.; Cui, J.; Zhang, L.; Zhang, Q.; Ke, C.; Huang, S. Recent progress in C-S bond formation via electron donor-acceptor photoactivation. Organic & biomolecular chemistry 2025. doi:10.1039/d4ob01951b
• Tan, F.; Fang, C.-Z.; Qiu, B.-S.; Sheng, H.; Tu, Y.-L.; Chen, X.-Y. Charge transfer complex enabled mechanochemical synthesis of chalcogenoacetylenes via alkynyl radicals. Organic Chemistry Frontiers 2025, 12, 649–654. doi:10.1039/d4qo01827c
• Shanthi., M.; Perumal, K.; Hemamalini, V.; Dandela, R.; Ramesh, S. Visible‐Light Mediated, Photocatalyst‐Free C−S Bond Formation via EDA Complex Formation. Asian Journal of Organic Chemistry 2025. doi:10.1002/ajoc.202400621
• Jeyaseelan, R.; Liu, W.; Zumbusch, J.; Næsborg, L. Methyl viologen as a catalytic acceptor for electron donor–acceptor photoinduced cyclization reactions. Green Chemistry 2025. doi:10.1039/d4gc05481d
• Feng, J.; Nicchio, L.; Liu, L.; Wu, Y.; Lu, K.; Protti, S.; Zhao, X. Recent advances in visible light-driven phosphine-mediated transformations. Organic Chemistry Frontiers 2025. doi:10.1039/d4qo02079k
• Huang, B. Photo- and electro-chemical synthesis of substituted pyrroles. Green Chemistry 2024, 26, 11773–11796. doi:10.1039/d4gc04495a
• Mandal, R. D.; Das, D.; Sarkar, A.; Saha, M.; Das, A. R.; Mahato, A.; Pramanik, A. Photoinduced Regioselective Decarbonylative and Decarboxylative C-O Bond Functionalizations: Approach toward Chemoselective Scissions of Isatoic Anhydride and Unraveling the Enroutes through Control Experiments and DFT Studies. The Journal of organic chemistry 2024, 89, 18069–18080. doi:10.1021/acs.joc.4c01856
• An, X.-D.; Wang, H.-Y.; Wang, L.-X.; Jiang, W.-T.; Xu, J.-J.; Sheng, Q.-Q.; Qin, Q.; Fu, Y. Visible-light-induced hydrosulfonylation of alkynes driven by electron-donor–acceptor (EDA) complexes. Tetrahedron Letters 2024, 153, 155368. doi:10.1016/j.tetlet.2024.155368
• Chen, H.; Wu, D.; Holzinger, J.; Götz, R.; Didier, D.; Schütz, A. K.; Schneider, S.; Kielkowski, P. Aryl Radicals Generated from Aryl Pinacol Boronates Modify Peptides and Proteins. European Journal of Organic Chemistry 2024. doi:10.1002/ejoc.202401246
• Yuan, N.; Chen, S.; Liu, Y.; Chen, M. C(sp2)-Arylsulfones Directly from Arylsulfonyl Chlorides with Boronic Acids by Photoactivation of Boosted EDA Complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 31, e202403487. doi:10.1002/chem.202403487
• Kolagkis, P. X.; Galathri, E. M.; Kokotos, C. G. Light-driven Michael addition of indoles to β-nitroolefins in aqueous medium. Catalysis Today 2024, 441, 114868. doi:10.1016/j.cattod.2024.114868
• Tu, J.-L.; Huang, B. Acyloxy, sulfate, and phosphate radicals as hydrogen atom transfer (HAT) agents for direct C(sp3)–H functionalization. RSC Sustainability 2024, 2, 3222–3234. doi:10.1039/d4su00520a
• Korivi, R.; Sureshbabu, P.; Busi, K. B.; Chakrabortty, S.; Mannathan, S. Visible light-induced denitrogenative annulation reaction of 1,2,3-benzotriazin-4(3H)-ones with alkenes and alkynes via electron donor–acceptor (EDA) complex formation: a sustainable approach to isoindolinone and isoquinolinone synthesis. Organic Chemistry Frontiers 2024, 11, 6184–6193. doi:10.1039/d4qo01053a
• Natarajan, P.; Partigya; Meena. Unactivated alkylsulfinic acids as an alkyl radical source for the synthesis of 3,3-dialkylindolin-2-ones via an electron donor–acceptor complex. New Journal of Chemistry 2024, 48, 17097–17105. doi:10.1039/d4nj03602f
• Mooney, D. T.; McKee, H.; Batch, T. S.; Drane, S.; Moore, P. R.; Lee, A.-L. Direct C-H amidation of 1,3-azoles: light-mediated, photosensitiser-free vs. thermal. Chemical communications (Cambridge, England) 2024, 60, 10752–10755. doi:10.1039/d4cc02742f
• Bokosi, F. R. B.; Shiels, O. J.; Trevitt, A. J.; Keaveney, S. T. Photoactivated Reactions without Traditional Photocatalysts: Electron-Donor Complexation of 1,2,3-Triazoles Initiates Denitrogenative Transformations. The Journal of organic chemistry 2024, 89, 13243–13252. doi:10.1021/acs.joc.4c01371
• Yang, S.; Guo, T.-T.; Ma, J.-B.; Jia, H.-T.; Liu, J.; Yan, S.-J. Radical Cascade Reaction of Heterocyclic Ketene Aminals with Thiocyanates Promoted by Visible Light: Synthesis of Functionalized Fused 2-Iminothiazolines. The Journal of organic chemistry 2024, 89, 13678–13690. doi:10.1021/acs.joc.4c01899
• Mondal, M.; Ghosh, S.; Lai, D.; Hajra, A. C-H Functionalization of Heteroarenes via Electron Donor-Acceptor Complex Photoactivation. ChemSusChem 2024, 17, e202401114. doi:10.1002/cssc.202401114

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