Supporting Information
Supporting Information contains Fourier difference maps (Figure S1), Hirshfeld surface analyses (Figures S2 and S3), optimized calculated structures (Figure S4), experimental and calculated geometric parameters (Tables S1 and S2) and vibrational assignments (Tables S3 and S4), 13C, COSY, HMBC and HSQC spectra (Figures S5–S12) and the full NMR characterization (Table S5) for both hydrazones reported herein. Hydrolytic stability of hdz-NO2 at pH 7.4 is also shown (Figure S13). Accession codes CCDC 2254324 and 2255022 contain the supplementary crystallographic data for the new hydrazones hdz-CH3 and hdz-NO2, respectively. These data can be obtained free of charge via https://www.ccdc.cam.ac.uk/data_request/cif, or by emailing data_request@ccdc.cam.ac.uk, or by contacting Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
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