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Manganese-catalyzed C–C and C–N bond formation with alcohols via borrowing hydrogen or hydrogen auto-transfer

Mohd Farhan Ansari, Atul Kumar Maurya, Abhishek Kumar and Saravanakumar Elangovan

Beilstein J. Org. Chem. 2024, 20, 1111–1166. https://doi.org/10.3762/bjoc.20.98

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Mohd Farhan Ansari, Atul Kumar Maurya, Abhishek Kumar and Saravanakumar Elangovan

Beilstein J. Org. Chem. 2024, 20, 1111–1166. https://doi.org/10.3762/bjoc.20.98

How to Cite

Ansari, M. F.; Maurya, A. K.; Kumar, A.; Elangovan, S. Beilstein J. Org. Chem. 2024, 20, 1111–1166. doi:10.3762/bjoc.20.98

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TY  - JOUR
A1  - Ansari, Mohd Farhan
A1  - Maurya, Atul Kumar
A1  - Kumar, Abhishek
A1  - Elangovan, Saravanakumar
T1  - Manganese-catalyzed C–C and C–N bond formation with alcohols via borrowing hydrogen or hydrogen auto-transfer
JF  - Beilstein Journal of Organic Chemistry
PY  - 2024///
VL  - 20
SP  - 1111
EP  - 1166
SN  - 1860-5397
DO  - 10.3762/bjoc.20.98
PB  - Beilstein-Institut
JA  - Beilstein J. Org. Chem.
UR  - https://doi.org/10.3762/bjoc.20.98
KW  - alcohols
KW  - alkylation
KW  - amines
KW  - borrowing hydrogen
KW  - hydrogen auto-transfer
KW  - manganese
N2  - Transition-metal-mediated “borrowing hydrogen" also known as hydrogen auto-transfer reactions allow the sustainable construction of C–C and C–N bonds using alcohols as hydrogen donors. In recent years, manganese complexes have been explored as efficient catalysts in these reactions. This review highlights the significant progress made in manganese-catalyzed C–C and C–N bond-formation reactions via hydrogen auto-transfer, emphasizing the importance of this methodology and manganese catalysts in sustainable synthesis strategies.
ER  -

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Scholarly Works

Swaathy, R.; Karthikeyan, S. Heterogeneous Mn@CeO2 Catalyst for α-Alkylation of Ketones with Alcohols via Hydrogen-Borrowing Strategy. ACS Omega 2025. doi:10.1021/acsomega.4c10938
Maurya, A. K.; Ansari, M. F.; Elangovan, S. Transition Metal Complexes Containing Selenium Ligands for Catalytic Reduction, Oxidation, and Hydrofunctionalization Reactions. Chemistry, an Asian journal 2025, e202401431. doi:10.1002/asia.202401431
Bernhardson, D. J.; Hubbell, A. K.; Singer, R. A.; Szpera, R.; Tcyrulnikov, S.; Vicini, A. C.; Allais, C. Recent Advances in Nonprecious Metal Catalysis. Organic Process Research & Development 2024, 28, 4240–4263. doi:10.1021/acs.oprd.4c00417

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