Expedient syntheses of the N-heterocyclic carbene precursor imidazolium salts IPr·HCl, IMes·HCl and IXy·HCl

Scholarly Works

• Wills, S. S.; Bailly, C.; Chetcuti, M. J. Towards Nickel-NHC Fluoro Complexes-Synthesis of Imidazolium Fluorides and Their Reactions with Nickelocene. Molecules (Basel, Switzerland) 2024, 29, 4493. doi:10.3390/molecules29184493
• Doleschal, M. E.; Kostenko, A.; Liu, J. Y.; Inoue, S. Isolation of a NHC-stabilized heavier nitrile and its conversion into an isonitrile analogue. Nature chemistry 2024. doi:10.1038/s41557-024-01618-6
• Twycross, D.; Tan, J.; Davey, C. J.; Leverett, A. R.; Cole, M. L.; McKay, A. I. Convenient Access to a N,N'‐bis(2,6‐terphenyl) Substituted N‐Heterocyclic Carbene. European Journal of Inorganic Chemistry 2024. doi:10.1002/ejic.202400226
• Xu, T.; Zhang, S.; He, Y.; Wang, C.; Wang, D.; Zhang, Q.; Fan, Z.; Fu, Z. Study on the micro-mechanism for the thermal stability of α-diimine nickel catalysts and active centers. Journal of Catalysis 2024, 436, 115632. doi:10.1016/j.jcat.2024.115632
• Lortie, J. L.; Davies, M.; Boyle, P. D.; Karttunen, M.; Ragogna, P. J. Chemoselective Staudinger Reactivity of Bis(azido)phosphines Supported with a π-Donating Imidazolin-2-iminato Ligand. Inorganic chemistry 2024, 63, 6335–6345. doi:10.1021/acs.inorgchem.4c00120
• Gillie, A. D.; Wakeling, M. G.; Greene, B. L.; Male, L.; Davies, P. W. A laterally-fused N-heterocyclic carbene framework from polysubstituted aminoimidazo[5,1-b]oxazol-6-ium salts. Beilstein journal of organic chemistry 2024, 20, 621–627. doi:10.3762/bjoc.20.54
• Grebennikov, N. O.; Boiko, D. A.; Prima, D. O.; Madiyeva, M.; Minyaev, M. E.; Ananikov, V. P. Boosting the generality of catalytic systems by the synergetic ligand effect in Pd-catalyzed C-N cross-coupling. Journal of Catalysis 2024, 429, 115240. doi:10.1016/j.jcat.2023.115240
• Janda, B. A.; Tran, J. A.; Chang, D. K.; Nerhood, G. C.; Maduka Ogba, O.; Liberman-Martin, A. L. Carbodiimide and Isocyanate Hydroboration by a Cyclic Carbodiphosphorane Catalyst. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202303095. doi:10.1002/chem.202303095
• Segato, J.; Aneggi, E.; Baratta, W.; Campagnolo, F.; Belpassi, L.; Belanzoni, P.; Zuccaccia, D. Experimental and Theoretical Investigation of Ion Pairing in Gold(III) Catalysts. Organometallics 2023, 42, 2973–2982. doi:10.1021/acs.organomet.3c00293
• Pasyukov, D. V.; Shevchenko, M. A.; Astakhov, A. V.; Minyaev, M. E.; Zhang, Y.; Chernyshev, V. M.; Ananikov, V. P. New class of RSO2-NHC ligands and Pd/RSO2-NHC complexes with tailored electronic properties and high performance in catalytic C-C and C-N bonds formation. Dalton transactions (Cambridge, England : 2003) 2023, 52, 12067–12086. doi:10.1039/d3dt02296j
• Khazipov, O. V.; Pyatachenko, A. S.; Chernyshev, V. M.; Ananikov, V. P. A Simple Protocol for the C−N Cross‐Coupling of Aryl Chlorides with Amines Applying Ni/NHC Catalysis. ChemCatChem 2023, 15. doi:10.1002/cctc.202300466
• Hayashi, K.; Liang, Q.; Philippi, F.; Song, D. Piano‐Stool Ruthenium N‐Heterocyclic Carbene Complexes for gem‐Specific Catalytic Dimerization of Terminal Alkynes. European Journal of Inorganic Chemistry 2023, 26. doi:10.1002/ejic.202300168
• Gonzalez, A.; Chen, T.-Y.; Demeshko, S.; Meyer, F.; Werncke, C. G. Synthesis, Properties, and Reactivity of a Linear NHC-Based Chromium(I) Silylamide. Organometallics 2023, 42, 1198–1204. doi:10.1021/acs.organomet.3c00013
• Joy, B. P.; Paul, S.; Sethy, S.; Gudimetla, V. B. Non‐Symmetrical Tetraaryl‐α‐Diimines via Transimination: A Promising Route for Non‐Symmetrical 1,3,4,5‐Tetraarylimidazolium Chlorides. ChemistrySelect 2023, 8. doi:10.1002/slct.202204605
• Medvedko, S.; Ströbele, M.; Wagner, J. P. Synthesis of Sterically Encumbered Thiourea S-Oxides through Direct Thiourea Oxidation. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 29, e202203005. doi:10.1002/chem.202203005
• Khazipov, O. V.; Shepelenko, K. E.; Soliev, S. B.; Nikolaeva, K. A.; Chernyshev, V. M.; Ananikov, V. P. Optimal Balance in the Catalyst Dynamics Enables C(2)−H Arylation of (Benz)imidazoles and (Benz)oxazoles by an In Situ‐Generated Ni/NHC System. ChemCatChem 2022, 14. doi:10.1002/cctc.202201055
• Rutz, P. M.; Grunenberg, J.; Kleeberg, C. Unsymmetrical Diborane(4) as a Precursor to PBP Boryl Pincer Complexes: Synthesis and Cu(I) and Pt(II) PBP Complexes with Unusual Structural Features. Organometallics 2022, 41, 3044–3054. doi:10.1021/acs.organomet.2c00457
• Alič, B.; Petrovčič, J.; Jelen, J.; Tavčar, G.; Iskra, J. Renewable Reagent for Nucleophilic Fluorination. The Journal of organic chemistry 2022, 87, 5987–5993. doi:10.1021/acs.joc.2c00247
• Wallach, C.; Klein, W.; Fässler, T. F. Nonagermanide Zintl Clusters with Mg2+ Counter Ions. Zeitschrift für anorganische und allgemeine Chemie 2022, 648. doi:10.1002/zaac.202200065
• Raeder, J.; Jördens, J. H.; Walter, M. D. Open samarocene and ytterbocenes and their adducts with. Australian Journal of Chemistry 2022, 75, 636–648. doi:10.1071/ch21326

Explore citations to this article at