A biphasic oxidation of alcohols to aldehydes and ketones using a simplified packed-bed microreactor

Scholarly Works

• Mei, F.; Lin, H.; Hu, L.; Dou, W.; Yang, H.; Xu, L. Homogeneous, heterogeneous, and enzyme catalysis in microfluidics droplets. Smart Molecules 2023, 1. doi:10.1002/smo.20220001
• Wan, L.; Jiang, M.; Cheng, D.; Liu, M.; Chen, F. Continuous flow technology-a tool for safer oxidation chemistry. Reaction Chemistry & Engineering 2022, 7, 490–550. doi:10.1039/d1re00520k
• Gambacorta, G.; Sharley, J. S.; Baxendale, I. R. A comprehensive review of flow chemistry techniques tailored to the flavours and fragrances industries. Beilstein journal of organic chemistry 2021, 17, 1181–1312. doi:10.3762/bjoc.17.90
• Jian, C.; Mengjing, Z.; Fuwei, X.; Junfeng, L.; Hongjun, Y.; Zhipeng, M. Research Progress on Microreactor Technology in Oxidation Reactions. Current Organic Chemistry 2021, 25, 1235–1245. doi:10.2174/1385272825666210319092545
• Lan, Z.; Lu, Y. Continuous nitration of o-dichlorobenzene in micropacked-bed reactor: process design and modelling. Journal of Flow Chemistry 2021, 11, 171–179. doi:10.1007/s41981-020-00132-3
• Lizandara-Pueyo, C.; Fan, X.; Ayats, C.; Pericàs, M. A. Calcium carbonate as heterogeneous support for recyclable organocatalysts. Journal of Catalysis 2021, 393, 107–115. doi:10.1016/j.jcat.2020.11.013
• Melone, L.; Bach, A.; Lamura, G.; Canepa, F.; Nivajärvi, R.; Olsson, V.; Kettunen, M. I. Cyclodextrin-Based Organic Radical Contrast Agents for in vivo Imaging of Gliomas. ChemPlusChem 2020, 85, 1171–1178. doi:10.1002/cplu.202000190
• Schulze, J. S.; Migenda, J.; Becker, M.; Schuler, S. M. M.; Wende, R. C.; Schreiner, P. R.; Smarsly, B. M. TEMPO-functionalized mesoporous silica particles as heterogeneous oxidation catalysts in flow. Journal of Materials Chemistry A 2020, 8, 4107–4117. doi:10.1039/c9ta12416k
• Folgueiras-Amador, A. A.; Wirth, T. Chapter 5:Electrochemistry under Flow Conditions. Flow Chemistry; The Royal Society of Chemistry, 2019; pp 153–198. doi:10.1039/9781788016094-00153
• Nair, V.; Colmenares, J. C.; Lisovytskiy, D. Ultrasound assisted ZnO coating in a microflow based photoreactor for selective oxidation of benzyl alcohol to benzaldehyde. Green Chemistry 2019, 21, 1241–1246. doi:10.1039/c8gc03131b
• von Keutz, T.; Cantillo, D.; Kappe, C. O. Enhanced mixing of biphasic liquid-liquid systems for the synthesis of gem-dihalocyclopropanes using packed bed reactors. Journal of Flow Chemistry 2019, 9, 27–34. doi:10.1007/s41981-018-0026-1
• Okuno, Y.; Kitagawa, Y.; Kamiya, S.; Hasegawa, A.; Kawashima, T.; Otani, K.; Aoki, S.; Kanno, J.; Isomura, S.; Sato, Y.; Takeda, K. Triphasic Continuous‐Flow Oxidation System for Alcohols Utilizing Graft‐Polymer‐Supported TEMPO. Asian Journal of Organic Chemistry 2018, 7, 1071–1074. doi:10.1002/ajoc.201800125
• Guo, S.; Yu, Z.; Yu, C. Kilogram-Scale Synthesis of 2,4-Dichloro-5-fluorobenzoic Acid by Air Oxidation under the Continuous-Flow Process. Organic Process Research & Development 2018, 22, 252–256. doi:10.1021/acs.oprd.7b00358
• Vanoye, L.; Yehouenou, L.; Philippe, R.; de Bellefon, C.; Fongarland, P.; Favre-Réguillon, A. Continuous flow oxidation of benzylic and aliphatic alcohols using bleach: process improvement by precise pH adjustment in flow with CO2. Reaction Chemistry & Engineering 2018, 3, 188–194. doi:10.1039/c7re00155j
• Plutschack, M. B.; Pieber, B.; Gilmore, K.; Seeberger, P. H. The Hitchhiker's Guide to Flow Chemistry. Chemical reviews 2017, 117, 11796–11893. doi:10.1021/acs.chemrev.7b00183
• Gemoets, H. P. L.; Su, Y.; Shang, M.; Hessel, V.; Luque, R.; Noël, T. Liquid phase oxidation chemistry in continuous-flow microreactors. Chemical Society reviews 2016, 45, 83–117. doi:10.1039/c5cs00447k
• Fernandes, A. E.; Riant, O.; Jonas, A. M.; Jensen, K. F. One “Click” to controlled bifunctional supported catalysts for the Cu/TEMPO-catalyzed aerobic oxidation of alcohols. RSC Advances 2016, 6, 36602–36605. doi:10.1039/c6ra05026c
• Abiev, R. S. Effect of contact-angle hysteresis on the pressure drop under slug flow conditions in minichannels and microchannels. Theoretical Foundations of Chemical Engineering 2015, 49, 414–421. doi:10.1134/s0040579515040223
• Trojanowicz, M. Flow chemistry vs. flow analysis. Talanta 2015, 146, 621–640. doi:10.1016/j.talanta.2015.07.043
• Ciriminna, R.; Pandarus, V.; Béland, F.; Xu, Y.-J.; Pagliaro, M. Heterogeneously Catalyzed Alcohol Oxidation for the Fine Chemical Industry. Organic Process Research & Development 2015, 19, 1554–1558. doi:10.1021/acs.oprd.5b00204

Explore citations to this article at