Structural studies on encapsulation of tetrahedral and octahedral anions by a protonated octaaminocryptand cage

I. Ravikumar, P. S. Lakshminarayanan, E. Suresh and Pradyut Ghosh
Beilstein J. Org. Chem. 2009, 5, No. 41. https://doi.org/10.3762/bjoc.5.41

Supporting Information

Experimental procedures, characterization data and copies of spectra (1H NMR and HRMS) of complexes 1, 2, and 3 as well as crystallographic data and tables of hydrogen bonding parameters of complexes 1, 2, and 3 are provided.

Supporting Information File 1: Experimental and analytical data.
Format: DOC Size: 334.5 KB Download

Cite the Following Article

Structural studies on encapsulation of tetrahedral and octahedral anions by a protonated octaaminocryptand cage
I. Ravikumar, P. S. Lakshminarayanan, E. Suresh and Pradyut Ghosh
Beilstein J. Org. Chem. 2009, 5, No. 41. https://doi.org/10.3762/bjoc.5.41

How to Cite

Ravikumar, I.; Lakshminarayanan, P. S.; Suresh, E.; Ghosh, P. Beilstein J. Org. Chem. 2009, 5, No. 41. doi:10.3762/bjoc.5.41

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Al Isawi, W. A.; Zeller, M.; Mezei, G. Where Fluoride Is Present, Hexafluorosilicate Might Be Encountered: Supramolecular Binding of the SiF62– Anion by Nanojars. ACS Omega 2024. doi:10.1021/acsomega.4c08535
  • Guchhait, T.; Roy, S.; Das, M.; Jena, S. P. Diversity in synthetic perchlorate anion receptors: Challenges and opportunities. Journal of Molecular Structure 2023, 1292, 136195. doi:10.1016/j.molstruc.2023.136195
  • Müller, C.; Scholten, K.; Engelage, E.; Merten, C. Synthesis and VCD Spectroscopic Characterization of a Series of Azacryptands from a Chiral Valine-Based Derivative of Tris(2-aminoethyl)amine (TREN). Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 29, e202302126. doi:10.1002/chem.202302126
  • Pitarch-Jarque, J.; Rissanen, K.; García-Granda, S.; Lopera, A.; Clares, M. P.; García-España, E.; Blasco, S. Water and oxoanion encapsulation chemistry in a 1H-pyrazole azacryptand. New Journal of Chemistry 2019, 43, 18915–18924. doi:10.1039/c9nj05231c
  • Gelmboldt, V. O.; Kravtsov, V. C.; Fonari, M. S. Ammonium hexafluoridosilicates: Synthesis, structures, properties, applications. Journal of Fluorine Chemistry 2019, 221, 91–102. doi:10.1016/j.jfluchem.2019.04.005
  • Puchta, R.; Begel, S.; van Eldik, R. Prediction of ion selectivity by quantum chemical calculations X : a recent (personal) review. Advances in Inorganic Chemistry 2019, 73, 445–505. doi:10.1016/bs.adioch.2018.10.005
  • Voloshin, Y. Z.; Belaya, I. G.; Krämer, R. Encapsulation by Covalent Capsules. The Encapsulation Phenomenon; Springer International Publishing, 2016; pp 9–138. doi:10.1007/978-3-319-27738-7_2
  • Begel, S.; Scheurer, A.; Puchta, R.; van Eldik, R. Host-Guest Complexes of [TriPip222], the Piperazine Analogue of [2.2.2]: Prediction of Ion Selectivity by Quantum Chemical Calculations VIII[#] †‡§. Zeitschrift für anorganische und allgemeine Chemie 2016, 642, 395–402. doi:10.1002/zaac.201600019
  • Haque, S. A.; Saeed, M. A.; Jahan, A.; Wang, J.; Leszczynski, J.; Hossain, M. A. Experimental and Theoretical Aspects of Anion Complexes with a Thiophene-Based Cryptand. Comments on modern chemistry. Part A, Comments on inorganic chemistry : a journal of critical discussion of the current literature 2016, 36, 305–326. doi:10.1080/02603594.2016.1171216
  • Begel, S.; Scheurer, A.; Puchta, R. Saalfrank-type {Fe2L3} host–guest complexes – prediction of ion selectivity by quantum chemical calculations VII. Journal of Coordination Chemistry 2015, 68, 3374–3387. doi:10.1080/00958972.2015.1076806
  • Bergamaschi, G.; Boiocchi, M.; Perrone, M. L.; Poggi, A.; Viviani, I.; Amendola, V. Mixing the spacers in azacryptands: effects on halide recognition. Dalton transactions (Cambridge, England : 2003) 2014, 43, 11352–11360. doi:10.1039/c4dt00886c
  • Begel, S.; Puchta, R.; van Eldik, R. Host-guest complexes of calix[4]tubes - prediction of ion selectivity by quantum chemical calculations VI. Journal of molecular modeling 2014, 20, 2200. doi:10.1007/s00894-014-2200-1
  • Basu, A.; Chutia, R.; Das, G. Dual modes of binding on the hexafluorosilicate anion by a C3v symmetric flexible tripodal amide ligand in solid state. CrystEngComm 2014, 16, 4886–4891. doi:10.1039/c4ce00529e
  • Begel, S.; Puchta, R.; van Eldik, R. Host-guest complexes of mixed glycol-bipyridine cryptands: prediction of ion selectivity by quantum chemical calculations, part V. Beilstein journal of organic chemistry 2013, 9, 1252–1268. doi:10.3762/bjoc.9.142
  • Sethuraman, V.; Nithianantham, S.; Muthiah, P. T. Self-assembly of hydrogen-bonded supramolecular structures based on hexafluorosilicate anion. Journal of Fluorine Chemistry 2012, 135, 38–44. doi:10.1016/j.jfluchem.2011.07.027
  • Ravikumar, I.; Ghosh, P. Recognition and separation of sulfate anions. Chemical Society reviews 2012, 41, 3077–3098. doi:10.1039/c2cs15293b
  • Ballester, P. Anion binding in covalent and self-assembled molecular capsules. Chemical Society reviews 2010, 39, 3810–3830. doi:10.1039/b926229f
  • Adarsh, N. N.; Tocher, D. A.; Ribas, J.; Dastidar, P. Metalla-macro-tricyclic cryptands: anion encapsulation and selective separation of sulfate via in situ crystallization. New Journal of Chemistry 2010, 34, 2458–2469. doi:10.1039/b9nj00556k
Other Beilstein-Institut Open Science Activities