Recent advances in carbocupration of α-heterosubstituted alkynes

Ahmad Basheer and Ilan Marek
Beilstein J. Org. Chem. 2010, 6, No. 77. https://doi.org/10.3762/bjoc.6.77

Cite the Following Article

Recent advances in carbocupration of α-heterosubstituted alkynes
Ahmad Basheer and Ilan Marek
Beilstein J. Org. Chem. 2010, 6, No. 77. https://doi.org/10.3762/bjoc.6.77

How to Cite

Basheer, A.; Marek, I. Beilstein J. Org. Chem. 2010, 6, No. 77. doi:10.3762/bjoc.6.77

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Agbaria, M.; Egbaria, N.; Nairoukh, Z. Dearomative spirocyclization of ynamides. Chemical science 2024, 15, 19136–19141. doi:10.1039/d4sc05541a
  • Takimoto, M.; Hou, Z. Regioselective Carbozincation and Further Functionalization of Allenamides Catalyzed by an N‐Heterocyclic Carbene (NHC)‐Copper Complex. Asian Journal of Organic Chemistry 2023, 12. doi:10.1002/ajoc.202300372
  • Rajesh, M.; Kumar, G. R. Recent Progress in Arylmetalative Cyclization/Annulation of Functionalized Alkynes with Organoboranes. Asian Journal of Organic Chemistry 2023, 12. doi:10.1002/ajoc.202300106
  • Blakemore, P. R.; Cao, Y. Enantiocontrolled Connective Synthesis of Allenes by Carbenoid Eliminative Cross-Coupling between α-(Methylthio)vinylcuprate Species and α-(Carbamoyloxy)alkylboronates. Synlett 2023, 34, 2200–2204. doi:10.1055/a-2072-2882
  • Silva, P. J. The Reaction Mechanism of the Cu(I) Catalyzed Alkylation of Heterosubstituted Alkynes. Catalysts 2022, 13, 17. doi:10.3390/catal13010017
  • Roy, S.; Mishra, A.; Sekhar Pati, S.; Behera, M.; Prakash Das, J. CuI Catalyzed Regio‐ and Stereo‐selective Hydroboration of Ynamides: α‐ and β‐Borylation via Hydro‐Cupration and Borylation. Asian Journal of Organic Chemistry 2022, 12. doi:10.1002/ajoc.202200505
  • Liu, L.; Wang, C.; Xi, Z. doi:10.1002/9781119448877.ch9
  • Cohen, Y.; Marek, I. Directed Regioselective Carbometallation of 1,2-Dialkyl-Substituted Cyclopropenes. Angewandte Chemie (International ed. in English) 2021, 60, 26368–26372. doi:10.1002/anie.202111382
  • Cohen, Y.; Marek, I. Directed Regioselective Carbometallation of 1,2‐Dialkyl‐Substituted Cyclopropenes. Angewandte Chemie 2021, 133, 26572–26576. doi:10.1002/ange.202111382
  • Konishi, A.; Nishimoto, Y.; Yasuda, M. Reaction Field for a Lewis Acid with a Tunable Factor for Selective Organic Synthesis. Middle Molecular Strategy; Springer Singapore, 2021; pp 225–260. doi:10.1007/978-981-16-2458-2_13
  • Silva, P. J.; Bernardo, C. E. P. Unveiling the Reaction Mechanism of the Das/Chechik/Marek Synthesis of Stereodefined Quaternary Carbon Centers. Applied Sciences 2021, 11, 5002. doi:10.3390/app11115002
  • Wang, P.-Y.; Massad, I.; Marek, I. Stereoselective Sc(OTf)3‐Catalyzed Aldol Reactions of disubstituted Silyl Enol Ethers of Aldehydes with Acetals. Angewandte Chemie (International ed. in English) 2021, 60, 12765–12769. doi:10.1002/anie.202101634
  • Wang, P.; Massad, I.; Marek, I. Stereoselective Sc(OTf)3‐Catalyzed Aldol Reactions of Disubstituted Silyl Enol Ethers of Aldehydes with Acetals. Angewandte Chemie 2021, 133, 12875–12879. doi:10.1002/ange.202101634
  • Kang, K.; Sakamoto, K.; Nishimoto, Y.; Yasuda, M. Synthesis of (Z)-β-(Carbonylamino)alkenylindium through Regioselective anti-Carboindation of Ynamides and Its Transformation to Multisubstituted Enamides. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 26, 4930–4934. doi:10.1002/chem.201905175
  • Kang, K.; Nishimoto, Y.; Yasuda, M. Regio- and Stereoselective Carboindation of Internal Alkynyl Ethers with Organosilicon or -stannane Nucleophiles. The Journal of organic chemistry 2019, 84, 13345–13363. doi:10.1021/acs.joc.9b01505
  • Shterenberg, A.; Haimov, E.; Smirnov, P.; Marek, I. Convergent and flexible approach to stereodefined polyhydroxylated fragments. Tetrahedron 2018, 74, 6761–6768. doi:10.1016/j.tet.2018.10.013
  • Kumar, G. R.; Kumar, R.; Rajesh, M.; Reddy, M. S. A nickel-catalyzed anti-carbometallative cyclization of alkyne-azides with organoboronic acids: synthesis of 2,3-diarylquinolines. Chemical communications (Cambridge, England) 2018, 54, 759–762. doi:10.1039/c7cc08408k
  • Baldassari, L. L.; de la Torre, A.; Li, J.; Lüdtke, D. S.; Maulide, N. Ynamide Preactivation Allows a Regio- and Stereoselective Synthesis of α,β-Disubstituted Enamides. Angewandte Chemie (International ed. in English) 2017, 56, 15723–15727. doi:10.1002/anie.201709128
  • Baldassari, L. L.; de la Torre, A.; Li, J.; Lüdtke, D. S.; Maulide, N. Regio- und stereoselektive Synthese α,β-disubstituierter Enamide durch Voraktivierung von Inamiden. Angewandte Chemie 2017, 129, 15929–15933. doi:10.1002/ange.201709128
  • Perego, L. A.; Blieck, R.; Groué, A.; Monnier, F.; Taillefer, M.; Ciofini, I.; Grimaud, L. Copper-Catalyzed Hydroamination of Allenes: from Mechanistic Understanding to Methodology Development. ACS Catalysis 2017, 7, 4253–4264. doi:10.1021/acscatal.7b00911
Other Beilstein-Institut Open Science Activities