A quantitative approach to nucleophilic organocatalysis

Scholarly Works

• An, F.; Brossette, J.; Jangra, H.; Wei, Y.; Shi, M.; Zipse, H.; Ofial, A. R. Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors. Chemical science 2024. doi:10.1039/d4sc04852k
• Behnke, A.; Eitzinger, A.; He, Y.; Antoni, P. W.; Ofial, A. R.; Hansmann, M. M. 2‐Methylene‐1,2‐dihydropyridines (2‐pyNHOs): Highly Nucleophilic Enamines. European Journal of Organic Chemistry 2024, 27. doi:10.1002/ejoc.202400373
• Silva Moratório de Moraes, R.; Tereza Miranda Martins, M.; Tavares de Almeida Pinto, G.; Couto Rodrigues, S.; Antunes do Nascimento, P.; Cardoso Cruz, C.; D'Oliveira Góes, K.; Claudia Cunha, A. An overview on generation and general properties of N-heterocyclic carbenes: Applications of 1,2,4-triazolium carbenes as metal free organocatalysts. Arabian Journal of Chemistry 2024, 17, 105527. doi:10.1016/j.arabjc.2023.105527
• Hensinger, M. J.; Eitzinger, A.; Trapp, O.; Ofial, A. R. Nucleophilicity of 4-(Alkylthio)-3-imidazoline Derived Enamines. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 30, e202302764. doi:10.1002/chem.202302764
• Eitzinger, A.; Reitz, J.; Antoni, P. W.; Mayr, H.; Ofial, A. R.; Hansmann, M. M. Mesoionische N‐Heterocyclische Olefine verschieben die obere Grenze der Nucleophilie‐Skala. Angewandte Chemie 2023, 135. doi:10.1002/ange.202309790
• Eitzinger, A.; Reitz, J.; Antoni, P. W.; Mayr, H.; Ofial, A. R.; Hansmann, M. M. Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins. Angewandte Chemie (International ed. in English) 2023, 62, e202309790. doi:10.1002/anie.202309790
• Nguyen, K.-U.; Zhang, Y.; Liu, Q.; Zhang, R.; Jin, X.; Taniguchi, M.; Miller, E. S.; Lindsey, J. S. Tolyporphins-Exotic Tetrapyrrole Pigments in a Cyanobacterium-A Review. Molecules (Basel, Switzerland) 2023, 28, 6132. doi:10.3390/molecules28166132
• Nguyen Tran, A. T.; Wu, Z.; Chung, D. T. M.; Nalaoh, P.; Lindsey, J. S. Synthesis of model southern rim structures of photosynthetic tetrapyrroles and phyllobilins. New Journal of Chemistry 2023, 47, 13626–13637. doi:10.1039/d3nj02515b
• Hensinger, M. J.; Closs, A. C.; Trapp, O.; Ofial, A. R. The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones. Chemical communications (Cambridge, England) 2023, 59, 8091–8094. doi:10.1039/d3cc01912h
• Hayashi, Y.; Han, X.; Mori, N. Secondary Amine-Mediated Domino Reaction for the Synthesis of Substituted Quinolines from Dicyanoalkenes and Enynals. Chemistry (Weinheim an der Bergstrasse, Germany) 2023, 29, e202301093. doi:10.1002/chem.202301093
• Nakano, Y.; Maddigan-Wyatt, J. T.; Lupton, D. W. Enantioselective Catalysis by the Umpolung of Conjugate Acceptors Involving N-Heterocyclic Carbene or Organophosphine 1,4-Addition. Accounts of chemical research 2023, 56, 1190–1203. doi:10.1021/acs.accounts.3c00063
• Eitzinger, A.; Ofial, A. R. Reactivity of electrophilic cyclopropanes. Pure and applied chemistry. Chimie pure et appliquee 2023, 95, 389–400. doi:10.1515/pac-2023-0209
• Chau Nguyen, K.; Nguyen Tran, A. T.; Wang, P.; Zhang, S.; Wu, Z.; Taniguchi, M.; Lindsey, J. S. Four Routes to 3-(3-Methoxy-1,3-dioxopropyl)pyrrole, a Core Motif of Rings C and E in Photosynthetic Tetrapyrroles. Molecules (Basel, Switzerland) 2023, 28, 1323. doi:10.3390/molecules28031323
• Gallarati, S.; van Gerwen, P.; Laplaza, R.; Vela, S.; Fabrizio, A.; Corminboeuf, C. OSCAR: an extensive repository of chemically and functionally diverse organocatalysts. Chemical science 2022, 13, 13782–13794. doi:10.1039/d2sc04251g
• Lakhdar, S. doi:10.1002/9783527832217.ch21
• Reactivity Models in Organic Chemistry. Reactivity and Mechanism in Organic Chemistry; The Royal Society of Chemistry, 2022; pp 54–100. doi:10.1039/9781837670970-00054
• Costa, A. M.; Castro‐Alvarez, A.; Fillot, D.; Vilarrasa, J. Computational Comparison of the Stability of Iminium Ions and Salts from Enals and Pyrrolidine Derivatives (Aminocatalysts). European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202200627
• Corbisiero, D.; Fantoni, T.; Ferrazzano, L.; Martelli, G.; Cantelmi, P.; Mattellone, A.; Palladino, C.; Monari, M.; Pedrazzani, R.; Tolomelli, A.; Cabri, W. Fast MacMillan's Imidazolidinone-Catalyzed Enantioselective Synthesis of Polyfunctionalized 4-Isoxazoline Scaffolds. ACS omega 2022, 7, 26919–26927. doi:10.1021/acsomega.2c03477
• Hayashi, Y. doi:10.1002/9781119736424.ch1
• Proppe, J.; Kircher, J. Uncertainty Quantification of Reactivity Scales. Chemphyschem : a European journal of chemical physics and physical chemistry 2022, 23, e202200061. doi:10.1002/cphc.202200061

Explore citations to this article at