Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds

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• Han, J.; Aceña, J. L.; Yasuda, N.; Uekusa, H.; Ono, T.; Soloshonok, V. A.; Klika, K. D. Carbonyl group coordination preferences in square-planar NiII and PdII complexes of pentadentate ligands by electron-withdrawing/donating substituents. Inorganica Chimica Acta 2015, 433, 3–12. doi:10.1016/j.ica.2015.04.029
• Acena, J. L.; Sorochinsky, A. E.; Soloshonok, V. A. Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 3: Michael addition reactions and miscellaneous transformations. Amino acids 2014, 46, 2047–2073. doi:10.1007/s00726-014-1764-5
• Han, J.; Ono, T.; Uekusa, H.; Klika, K. D.; Soloshonok, V. A. Substituent-controlled preference of carbonyl group-metal coordination in d8 metal complexes with non-symmetric pentadentate ligands. Structural and stereochemical aspects. Dalton transactions (Cambridge, England : 2003) 2014, 43, 5375–5381. doi:10.1039/c3dt53312c
• Moriwaki, H.; Resch, D.; Li, H.; Ojima, I.; Takeda, R.; Aceña, J. L.; Soloshonok, V. A. Synthesis and stereochemical assignments of diastereomeric Ni(II) complexes of glycine Schiff base with (R)-2-(N-{2-[N-alkyl-N-(1-phenylethyl)amino]acetyl}amino)benzophenone; a case of configurationally stable stereogenic nitrogen. Beilstein journal of organic chemistry 2014, 10, 442–448. doi:10.3762/bjoc.10.41

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