Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization–(2 + 2) cycloaddition

Scholarly Works

• Ito, T. Experiments. Springer Theses; Springer Nature Singapore, 2024; pp 67–129. doi:10.1007/978-981-97-0787-4_6
• Ito, T. Asymmetric Organocatalytic [2 + 2] Cycloaddition Affording Bicyclo[n.2.0]alkenes. Springer Theses; Springer Nature Singapore, 2024; pp 53–64. doi:10.1007/978-981-97-0787-4_4
• Zhou, H.; Zhang, P.; List, B. The Silicon–Hydrogen Exchange Reaction: Catalytic Kinetic Resolution of 2-Substituted Cyclic Ketones. Synlett 2021, 32, 1953–1956. doi:10.1055/a-1670-5829
• Pu, L.-Y.; Yang, F.; Chen, J.-Q.; Xiong, Y.; Bin, H.-Y.; Xie, J.-H.; Zhou, Q.-L. Enantioselective Total Syntheses of Pentacyclic Homoproaporphine Alkaloids. Organic letters 2020, 22, 7526–7530. doi:10.1021/acs.orglett.0c02720
• Zhou, H.; Bae, H. Y.; Leutzsch, M.; Kennemur, J. L.; Bécart, D.; List, B. The Silicon-Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes. Journal of the American Chemical Society 2020, 142, 13695–13700. doi:10.1021/jacs.0c06677
• Mogi, Y.; Inanaga, K.; Tokuyama, H.; Ihara, M.; Yamaoka, Y.; Yamada, K.-i.; Takasu, K. Rapid Assembly of Protoilludane Skeleton through Tandem Catalysis: Total Synthesis of Paesslerin A and Its Structural Revision. Organic letters 2019, 21, 3954–3958. doi:10.1021/acs.orglett.9b01089
• Zhao, W.; Sun, J. Triflimide (HNTf2) in Organic Synthesis. Chemical reviews 2018, 118, 10349–10392. doi:10.1021/acs.chemrev.8b00279
• Tsuchimochi, I.; Kitamura, Y.; Aoyama, H.; Akai, S.; Nakai, K.; Yoshimitsu, T. Total synthesis of (−)-agelastatin A: an SH2′ radical azidation strategy. Chemical communications (Cambridge, England) 2018, 54, 9893–9896. doi:10.1039/c8cc05697h
• Kurahashi, K.; Yamaoka, Y.; Takemoto, Y.; Takasu, K. Silyl enol etherification by a Tf2NH/amine co-catalytic system for minimizing hazardous waste generation. Reaction Chemistry & Engineering 2018, 3, 626–630. doi:10.1039/c8re00039e
• Takasu, K. Synthesis of Multisubstituted Silyloxy‐based Donor‐Acceptor Cyclobutanes by an Acid‐Catalyzed [2+2] Cycloaddition. Israel Journal of Chemistry 2016, 56, 488–498. doi:10.1002/ijch.201500096
• Sai, M.; Yamamoto, H. Chiral Brønsted Acid as a True Catalyst: Asymmetric Mukaiyama Aldol and Hosomi-Sakurai Allylation Reactions. Journal of the American Chemical Society 2015, 137, 7091–7094. doi:10.1021/jacs.5b04168
• Yamaoka, Y.; Takasu, K. Methods and Applications of Cycloaddition Reactions in Organic Syntheses; Wiley, 2014; pp 115–134. doi:10.1002/9781118778173.ch04
• Takasu, K. Auto-tandem Catalysis of Triflic Imide in Organic Synthesis. Journal of Synthetic Organic Chemistry, Japan 2014, 72, 770–780. doi:10.5059/yukigoseikyokaishi.72.770
• Briones, J. F.; Davies, H. M. L. Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers. Journal of the American Chemical Society 2013, 135, 13314–13317. doi:10.1021/ja407179c

Explore citations to this article at