Gallium-containing polymer brush film as efficient supported Lewis acid catalyst in a glass microreactor

Rajesh Munirathinam, Roberto Ricciardi, Richard J. M. Egberink, Jurriaan Huskens, Michael Holtkamp, Herbert Wormeester, Uwe Karst and Willem Verboom
Beilstein J. Org. Chem. 2013, 9, 1698–1704. https://doi.org/10.3762/bjoc.9.194

Supporting Information

Supporting Information File 1: Conversion of cinnamaldehyde oxime (1, 25 µM in acetonitrile) catalyzed by gallium in a microreactor at different temperatures.
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Gallium-containing polymer brush film as efficient supported Lewis acid catalyst in a glass microreactor
Rajesh Munirathinam, Roberto Ricciardi, Richard J. M. Egberink, Jurriaan Huskens, Michael Holtkamp, Herbert Wormeester, Uwe Karst and Willem Verboom
Beilstein J. Org. Chem. 2013, 9, 1698–1704. https://doi.org/10.3762/bjoc.9.194

How to Cite

Munirathinam, R.; Ricciardi, R.; Egberink, R. J. M.; Huskens, J.; Holtkamp, M.; Wormeester, H.; Karst, U.; Verboom, W. Beilstein J. Org. Chem. 2013, 9, 1698–1704. doi:10.3762/bjoc.9.194

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Scholarly Works

  • Zhang, Y.; Li, M.; Li, B.; Sheng, W. Surface Functionalization with Polymer Brushes via Surface-Initiated Atom Transfer Radical Polymerization: Synthesis, Applications, and Current Challenges. Langmuir : the ACS journal of surfaces and colloids 2024, 40, 5571–5589. doi:10.1021/acs.langmuir.3c03647
  • Examples of Inorganic and Organometallic Polymers. Fundamentals of Inorganic and Organometallic Polymer Science; Royal Society of Chemistry, 2023; pp 173–193. doi:10.1039/bk9781837672325-00173
  • Timmerhuis, N. A.; Wood, J. A.; Lammertink, R. G. Connecting experimental degradation kinetics to theoretical models for photocatalytic reactors: The influence of mass transport limitations. Chemical Engineering Science 2021, 245, 116835. doi:10.1016/j.ces.2021.116835
  • Ahmed, S. M.; Hussain, F. H. S.; Quadrelli, P. 9-Anthraldehyde oxime: a synthetic tool for variable applications. Monatshefte für Chemie - Chemical Monthly 2020, 151, 1643–1658. doi:10.1007/s00706-020-02695-2
  • Doku, G. N.; Agbozo, W. K.; Haswell, S. J.; McCreedy, T. Phosphomolybdenum Blue Detection – A Review of Characteristics, Achievements, Challenges and Future Prospects. Ghana Journal of Science 2020, 61, 43–49. doi:10.4314/gjs.v61i1.4
  • Mandoli, A. Catalyst Immobilization; Wiley, 2019; pp 257–306. doi:10.1002/9783527817290.ch8
  • Colella, M.; Carlucci, C.; Luisi, R. Supported Catalysts for Continuous Flow Synthesis. Topics in current chemistry (Cham) 2018, 376, 46. doi:10.1007/s41061-018-0225-0
  • Ruiz-Muelle, A. B.; Contreras-Cáceres, R.; Oña-Burgos, P.; Rodríguez-Diéguez, A.; López-Romero, J. M.; Fernández, I. Polyacrylic acid polymer brushes as substrates for the incorporation of anthraquinone derivatives. Unprecedented application of decorated polymer brushes on organocatalysis. Applied Surface Science 2018, 428, 566–578. doi:10.1016/j.apsusc.2017.09.150
  • Da Silva, B. Ph.D. Thesis, Nov 18, 2015.
  • Salvio, R. The guanidinium unit in the catalysis of phosphoryl transfer reactions: from molecular spacers to nanostructured supports. Chemistry (Weinheim an der Bergstrasse, Germany) 2015, 21, 10960–10971. doi:10.1002/chem.201500789
  • Munirathinam, R.; Huskens, J.; Verboom, W. Supported Catalysis in Continuous-Flow Microreactors. Advanced Synthesis & Catalysis 2015, 357, 1093–1123. doi:10.1002/adsc.201401081
  • Savelli, C.; Salvio, R. Guanidine‐Based Polymer Brushes Grafted onto Silica Nanoparticles as Efficient Artificial Phosphodiesterases. Chemistry (Weinheim an der Bergstrasse, Germany) 2015, 21, 5856–5863. doi:10.1002/chem.201406526
  • Fernandes, A. E.; Ye, Q.; Collard, L.; Le Duff, C. S.; D'Haese, C.; Deumer, G.; Haufroid, V.; Nysten, B.; Riant, O.; Jonas, A. M. Effects of Thickness and Grafting Density on the Activity of Polymer-Brush-Immobilized Tris(triazolyl) Copper(I) Catalysts. ChemCatChem 2015, 7, 856–864. doi:10.1002/cctc.201402913
  • Munirathinam, R.; Leoncini, A.; Huskens, J.; Wormeester, H.; Verboom, W. Wall-Coated Polymer Brushes as Support for Chiral Organocatalysts in Microreactors. Journal of Flow Chemistry 2015, 5, 37–42. doi:10.1556/jfc-d-14-00034
  • Munirathinam, R.; Huskens, J.; Verboom, W. Piperazine-Containing Polymer Brush Layer as Supported Base Catalyst in a Glass Microreactor. Journal of Flow Chemistry 2014, 4, 135–139. doi:10.1556/jfc-d-14-00020
  • Ricciardi, R.; Munirathinam, R.; Huskens, J.; Verboom, W. Improved catalytic activity and stability using mixed sulfonic acid- and hydroxy-bearing polymer brushes in microreactors. ACS applied materials & interfaces 2014, 6, 9386–9392. doi:10.1021/am5017717
  • Glasnov, T. N. Highlights from the Flow Chemistry Literature 2013 (Part 3). Journal of Flow Chemistry 2013, 3, 132–140. doi:10.1556/jfc-d-13-00026
  • Ricciardi, R.; Huskens, J.; Verboom, W. Heterogeneous acid catalysis using a perfluorosulfonic-acid monolayer-functionalized microreactor. Journal of Flow Chemistry 2013, 3, 127–131. doi:10.1556/jfc-d-13-00024

Patents

  • DINKAR SUMI; DHANABALAN ANANTHARAMAN. Moisture curable organopolysiloxane compositions. US 9663657 B2, May 30, 2017.
  • PATEL MIHIRKUMAR MAHESHBAI; DHANABALAN ANANTHARAMAN; DINKAR SUMI; SARKAR ALOK. Non-metal catalyzed room temperature moisture curable organopolysiloxane compositions. US 9605113 B2, March 28, 2017.
  • BYRNE CHRISTOPHER. Moisture curable organopolysiloxane composition. US 9527959 B2, Dec 27, 2016.
  • DINKAR SUMI; DHANABALAN ANANTHARAMAN. Moisture curable organopolysiloxane compositions. US 9523002 B2, Dec 20, 2016.
  • PATEL MIHIRKUMAR; DHANABALAN ANANTHARAMAN; DINKAR SUMI; KARAMBELKAR VIVEK. Moisture curable organopolysiloxane compositions. US 9493691 B2, Nov 15, 2016.
  • DINKAR SUMI; MAHESHBAI MIHIRKUMAR PATEL; DHANABALAN ANANTHARAMAN. Moisture curable organopolysiloxane composition. US 9394443 B2, July 19, 2016.
  • DINKAR SUMI. MOISTURE CURABLE SILICONE COMPOSITION. WO 2015119904 A1, Aug 13, 2015.
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