The chemistry of amine radical cations produced by visible light photoredox catalysis

Scholarly Works

• Jazani, A. M.; Yilmaz, G.; Baumer, M.; Sobieski, J.; Bernhard, S.; Matyjaszewski, K. Unraveling the Roles of Amines in Atom Transfer Radical Polymerization in the Dark. Journal of the American Chemical Society 2025. doi:10.1021/jacs.4c18496
• Bariwal, J.; Van der Eycken, E. Harnessing Visible/UV Light for the Activation and/or Functionalization of C-H Bonds: Metal- and Photocatalyst-Free Approach. Chemical record (New York, N.Y.) 2025, e202400227. doi:10.1002/tcr.202400227
• Serna-Galvis, E. A.; Mendoza-Merlano, C.; Arboleda-Echavarría, J.; Torres-Palma, R. A.; Echavarría-Isaza, A. Comparison of three different zeolites to activate peroxymonosulfate for the degradation of the pharmaceutical ciprofloxacin in water. Environmental science and pollution research international 2025, 32, 6856–6870. doi:10.1007/s11356-025-35994-4
• Yu, Z.; Inoue, D.; Sawada, N.; Takinami, H.; Ghosh, T.; Sasaki, N.; Abe, M.; Taniguchi, T.; Koike, T.; Nokami, T. Photochemical transformations of glycosyl bromides in the presence of amines. Carbohydrate research 2025, 552, 109436. doi:10.1016/j.carres.2025.109436
• Zhang, X.; Jin, G.; Zhang, Q.; Sun, C.; Han, Y.; Dou, C.; Yuan, Z.; Xia, L.; Yun, S.; Chao, M.; Shen, D. Flavoenzyme‐inspired Reductive Dehalogenation of α‐Br and α‐Cl Carbonyl Compounds with Riboflavin Tetraacetate as Photocatalyst. Asian Journal of Organic Chemistry 2025. doi:10.1002/ajoc.202400709
• Sudrajat, H.; Hsu, H.; Jérôme, F.; Colmenares, J. C. Mechanoredox‐Catalyzed Organic Synthesis with Piezoelectric Materials: Quo Vadis?. ChemCatChem 2025, 17. doi:10.1002/cctc.202401814
• Matsukuma, K.; Tayu, M.; Ogino, T.; Ohrui, S.; Noji, M.; Hayashi, S.; Saito, N. Photoredox/Sulfide Dual Catalysis for Modular Synthesis of Multi-substituted Furan Rings via Catalytic Indirect Reductive Quenching. Chemistry, an Asian journal 2025, 20, e202401442. doi:10.1002/asia.202401442
• Düker, J.; Philipp, M.; Lentner, T.; Cadge, J. A.; Lavarda, J. E. A.; Gschwind, R. M.; Sigman, M. S.; Ghosh, I.; König, B. Cross-Coupling Reactions with Nickel, Visible Light, and tert-Butylamine as a Bifunctional Additive. ACS catalysis 2024, 15, 817–827. doi:10.1021/acscatal.4c07185
• Singh, P. P.; Singh, S. P.; Mishra, M.; Tivari, S.; Singh, P. K.; Srivastava, V. Visible-Light-Induced Acridinium-Catalyzed Acylation of Isoquinolines with Aldehydes via HAT. Synlett 2024. doi:10.1055/a-2500-6651
• Anita, Y.; Woo, S. K.; Atriardi, S. R. Harnessing Photoredox and Weak Brønsted Base Dual Catalysis for Selective C(sp3)–H Bond Activation. Synthesis 2024, 57, 953–964. doi:10.1055/s-0043-1775423
• Lemmerer, M.; Tona, V.; Just, D.; Vavrík, M.; Maryasin, B.; Di Mauro, G.; B. zur Bonsen, A.; Kaiser, D.; Maulide, N. Iodid‐Anion ermöglicht eine reduktive Kreuz‐Elektrophil‐Kupplung zur Herstellung tertiärer Amine. Angewandte Chemie 2024, 137. doi:10.1002/ange.202409688
• Lemmerer, M.; Tona, V.; Just, D.; Vavrík, M.; Maryasin, B.; Di Mauro, G.; Zur Bonsen, A. B.; Kaiser, D.; Maulide, N. Iodide Anion Enables a Reductive Cross-Electrophile Coupling for Preparing Tertiary Amines. Angewandte Chemie (International ed. in English) 2024, 64, e202409688. doi:10.1002/anie.202409688
• Sobieski, J.; Gorczyński, A.; Jazani, A. M.; Yilmaz, G.; Matyjaszewski, K. Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization. Angewandte Chemie 2024, 137. doi:10.1002/ange.202415785
• Sobieski, J.; Gorczyński, A.; Jazani, A. M.; Yilmaz, G.; Matyjaszewski, K. Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization. Angewandte Chemie (International ed. in English) 2024, 64, e202415785. doi:10.1002/anie.202415785
• Dhingra, K.; Saini, N.; Kumar, A.; Kailasam, K. Leveraging cooperative photocatalysis for the concurrent production of solar fuels and value-added chemicals: mediated by a metal-free porphyrin-based polymeric framework. Journal of Materials Chemistry A 2024, 12, 29657–29668. doi:10.1039/d4ta04445b
• Mondo, G. B.; da Silva Ribeiro, C. A.; Schlüter, L. G.; Bellettini, I. C.; Pavlova, E.; Giacomelli, F. C. One-pot bottom-up synthesis of gold nanoparticles mediated by nitrogen-containing polymers: The role of chain features and environmental conditions. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2024, 703, 135116. doi:10.1016/j.colsurfa.2024.135116
• Cvek, M.; Moini Jazani, A.; De Luca Bossa, F.; Bernat, R.; Kapil, K.; Matyjaszewski, K. Copper and ZnO Dual-Catalyzed Photo-Assisted Depolymerization of Poly(Methyl Methacrylate) without Deoxygenation. European Polymer Journal 2024, 220, 113429. doi:10.1016/j.eurpolymj.2024.113429
• Czyz, M. L.; Horngren, T. H.; Kondopoulos, A. J.; Franov, L. J.; Forni, J. A.; Pham, L. N.; Coote, M. L.; Polyzos, A. Photocatalytic generation of alkyl carbanions from aryl alkenes. Nature Catalysis 2024, 7, 1316–1329. doi:10.1038/s41929-024-01237-x
• Franco, F.; Boselli, M. F.; Medici, F. Nitrogen-Centered Radicals in Visible-Light-Promoted Reactions. SynOpen 2024, 8, 273–299. doi:10.1055/a-2441-3612
• Wang, J.; Fang, H.; Zhong, Z.; Huang, H.; Liang, X.; Yuan, Y.; Zhou, W.; Vione, D. Predicting pKa Values of Para-Substituted Aniline Radical Cations vs. Stable Anilinium Ions in Aqueous Media. Molecules (Basel, Switzerland) 2024, 29, 4522. doi:10.3390/molecules29194522

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