Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

Grégory Landelle, Armen Panossian, Sergiy Pazenok, Jean-Pierre Vors and Frédéric R. Leroux
Beilstein J. Org. Chem. 2013, 9, 2476–2536. https://doi.org/10.3762/bjoc.9.287

Cite the Following Article

Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation
Grégory Landelle, Armen Panossian, Sergiy Pazenok, Jean-Pierre Vors and Frédéric R. Leroux
Beilstein J. Org. Chem. 2013, 9, 2476–2536. https://doi.org/10.3762/bjoc.9.287

How to Cite

Landelle, G.; Panossian, A.; Pazenok, S.; Vors, J.-P.; Leroux, F. R. Beilstein J. Org. Chem. 2013, 9, 2476–2536. doi:10.3762/bjoc.9.287

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Levet, V.; Ramesh, B.; Wang, C.; Besset, T. C-H Trifluoromethylthiolation of aldehyde hydrazones. Beilstein journal of organic chemistry 2024, 20, 2883–2890. doi:10.3762/bjoc.20.242
  • Vincent, É.; Brioche, J. Silver-Catalyzed Carbofluorination of Olefins and α-Fluoroolefins with Carbamoyl Radicals. Chemistry (Weinheim an der Bergstrasse, Germany) 2024, 30, e202401419. doi:10.1002/chem.202401419
  • Huang, Z.-M.; Sun, Y.; Wang, Y.; Wang, X.-W. Unveiling the Selectivity of Ru(II)-Catalyzed C-H Activation for Defluorinative Cyclization of 2-Arylbenzimidazole and Trifluoromethyl Diazo: A DFT Study. The Journal of organic chemistry 2024, 89, 7982–7990. doi:10.1021/acs.joc.4c00629
  • Lu, X.-Y.; Huang, R.; Wang, Z.-Z.; Zhang, X.; Jiang, F.; Yang, G.-X.; Shui, F.-Y.; Su, M.-X.; Sun, Y.-X.; Sun, H.-L. Photoinduced Decarboxylative Difluoroalkylation and Perfluoroalkylation of α-Fluoroacrylic Acids. The Journal of organic chemistry 2024, 89, 6494–6505. doi:10.1021/acs.joc.4c00684
  • Shigeno, M.; Kiriyama, M.; Izumi, K.; Sasaki, K.; Sasamoto, O.; Nozawa-Kumada, K.; Kondo, Y. LiO-t-Bu/CsF-Mediated Formal Hydrolysis of Trifluoromethyl Arenes. Synthesis 2023, 56, 1438–1448. doi:10.1055/a-2236-0209
  • Doche, F.; Poisson, T.; Besset, T. Photocatalytic α-Trifluoromethylthiolation of N-Acyl Amines. ACS Catalysis 2023, 13, 14112–14120. doi:10.1021/acscatal.3c03249
  • Zhong, T.; Gu, C.; Li, Y.; Huang, J.; Han, J.; Zhu, C.; Han, J.; Xie, J. Manganese/Cobalt Bimetallic Relay Catalysis for Divergent Dehydrogenative Difluoroalkylation of Alkenes. Angewandte Chemie 2023, 135. doi:10.1002/ange.202310762
  • Zhong, T.; Gu, C.; Li, Y.; Huang, J.; Han, J.; Zhu, C.; Han, J.; Xie, J. Manganese/Cobalt Bimetallic Relay Catalysis for Divergent Dehydrogenative Difluoroalkylation of Alkenes. Angewandte Chemie (International ed. in English) 2023, 62, e202310762. doi:10.1002/anie.202310762
  • Bernd, J.; Terfort, A. Flow electrosynthesis for efficient O-trifluoromethylation of electron-deficient phenols. Electrochemistry Communications 2023, 154, 107545. doi:10.1016/j.elecom.2023.107545
  • Wang, K.; Kong, W. Synthesis of Fluorinated Compounds by Nickel-Catalyzed Defluorinative Cross-Coupling Reactions. ACS Catalysis 2023, 13, 12238–12268. doi:10.1021/acscatal.3c02993
  • Monsigny, L.; Doche, F.; Besset, T. Transition-metal-catalyzed C-H bond activation as a sustainable strategy for the synthesis of fluorinated molecules: an overview. Beilstein journal of organic chemistry 2023, 19, 448–473. doi:10.3762/bjoc.19.35
  • Wang, F.; Zhang, Q.; Tong, S.; Wang, M. Arene C–H bond trifluoromethylation reactions involving different high valent arylcopper intermediates. SCIENTIA SINICA Chimica 2023, 53, 522–528. doi:10.1360/ssc-2022-0234
  • Das, S.; K.Indurthi, H.; Saha, P.; Sharma, D. K. K2S2O8‐Glucose‐Mediated Metal‐Free Oxidative Trifluoromethylation of Indoles with Langlois' Reagent on the C2 Position. ChemistrySelect 2023, 8. doi:10.1002/slct.202203939
  • Gao, H.; Hu, L.; Hu, Y.; Lv, X.; Wu, Y.-B.; Lu, G. Weak Electrostatic Interactions with Bisphosphine Ligands Facilitate Reductive Elimination of PhCF3 from Pd(II) Complexes. Chemistry, an Asian journal 2023, 18, e202201219. doi:10.1002/asia.202201219
  • Shen, Z.-J.; Zhu, C.; Zhang, X.; Yang, C.; Rueping, M.; Guo, L.; Xia, W. Organoboron Reagent-Controlled Selective (Deutero)Hydrodefluorination. Angewandte Chemie (International ed. in English) 2023, 62, e202217244. doi:10.1002/anie.202217244
  • Shen, Z.; Zhu, C.; Zhang, X.; Yang, C.; Rueping, M.; Guo, L.; Xia, W. Organoboron Reagent‐Controlled Selective (Deutero)Hydrodefluorination. Angewandte Chemie 2023, 135. doi:10.1002/ange.202217244
  • Fruit, C. doi:10.1002/9783527834242.chf0232
  • Lalloo, N.; Brigham, C. E.; Sanford, M. S. Mechanism-Driven Development of Group 10 Metal-Catalyzed Decarbonylative Coupling Reactions. Accounts of chemical research 2022, 55, 3430–3444. doi:10.1021/acs.accounts.2c00496
  • Solomon, N. S. D.; Bhadbhade, M.; Tian, R.; Keaveney, S. T. Nickel and Palladium Catalyzed C−H Trifluoromethylation using Trifluoromethyliodide: Investigations into New Reactivity. ChemCatChem 2022, 14. doi:10.1002/cctc.202200918
  • Prabhakar, N. S.; Kumar, S.; Gupta, P. K.; Singh, K. N. Visible-Light-Induced Photocatalytic Trifluoromethylation of Bunte Salts: Easy Access to Trifluoromethylthiolated Synthons. The Journal of organic chemistry 2022, 87, 11112–11120. doi:10.1021/acs.joc.2c01353
Other Beilstein-Institut Open Science Activities