Inter- and intramolecular enantioselective carbolithiation reactions

Scholarly Works

• Scrivener, S. G.; Wang, Y.-M. A C-H functionalization approach to diverse nitrogenous scaffolds through conjugate addition of catalytic allyliron nucleophiles. Chemical science 2024, 15, 8850–8857. doi:10.1039/d4sc00655k
• Semba, K. Olefin Difunctionalization With Two Different Atoms; 1,2-Carbofunctionalization of Olefins With Heteroatoms Other than O and N. Comprehensive Chirality; Elsevier, 2024; pp 371–405. doi:10.1016/b978-0-32-390644-9.00017-2
• Kacprzak, K.; Wojaczyńska, E.; Trochimczuk, A.; Steppeler, F.; Wojaczyński, J. doi:10.1002/9783527834204.ch10
• Cigan, E.; Eggbauer, B.; Schrittwieser, J. H.; Kroutil, W. The role of biocatalysis in the asymmetric synthesis of alkaloids – an update. RSC advances 2021, 11, 28223–28270. doi:10.1039/d1ra04181a
• Augros, D.; Comoy, C.; Fort, Y.; Leroux, F. R.; Panossian, A. The Winding Road towards an Atropo-enantioselective ‘ARYNE Coupling’. European Journal of Organic Chemistry 2021, 2021, 1971–1978. doi:10.1002/ejoc.202100087
• Mandigma, M. J. P.; Domański, M.; Barham, J. P. C-Alkylation of alkali metal carbanions with olefins. Organic & biomolecular chemistry 2020, 18, 7697–7723. doi:10.1039/d0ob01180k
• Marsico, G.; Scafato, P.; Belviso, S.; Superchi, S. Regio- and stereoselective intermolecular carbolithiation reactions. RSC advances 2020, 10, 32581–32601. doi:10.1039/d0ra06101h
• Carral-Menoyo, A.; Sotomayor, N.; Lete, E. Palladium-catalysed Heck-type alkenylation reactions in the synthesis of quinolines. Mechanistic insights and recent applications. Catalysis Science & Technology 2020, 10, 5345–5361. doi:10.1039/d0cy00789g
• Guyon, H.; Castanet, A.-S.; Boussonnière, A. Computational Insight into 1,2-Diamine, -Diether, and -Amino Ether Chiral Ligand-Mediated Carbolithiation: A Case of Enantioinduction Reversal. The Journal of organic chemistry 2020, 85, 8933–8943. doi:10.1021/acs.joc.0c00832
• Alazet, S.; West, M. S.; Patel, P.; Rousseaux, S. A. L. Synthesis of Nitrile‐Bearing Quaternary Centers by an Equilibrium‐Driven Transnitrilation and Anion‐Relay Strategy. Angewandte Chemie 2019, 131, 10406–10410. doi:10.1002/ange.201903215
• Alazet, S.; West, M. S.; Patel, P.; Rousseaux, S. A. L. Synthesis of Nitrile‐Bearing Quaternary Centers by an Equilibrium‐Driven Transnitrilation and Anion‐Relay Strategy. Angewandte Chemie (International ed. in English) 2019, 58, 10300–10304. doi:10.1002/anie.201903215
• Liu, S.; Gray, D. L.; Zhu, L.; Girolami, G. S. Lithium–Olefin π-Complexes and the Mechanism of Carbolithiation: Synthesis, Solution Behavior, and Crystal Structure of (2,2-Dimethylpent-4-en-1-yl)lithium. Organometallics 2019, 38, 2199–2210. doi:10.1021/acs.organomet.9b00169
• Simon, M.; Karaghiosoff, K.; Knochel, P. Diastereoselective Intramolecular Carbolithiations of Stereodefined Secondary Alkyllithiums Bearing a Remote Alkynylsilane. Organic letters 2018, 20, 3518–3521. doi:10.1021/acs.orglett.8b01290
• Azcargorta, A. R.; Coya, E.; Panaite, A. M.; Sotomayor, N.; Lete, E. Intramolecular Addition of Heteroaryllithium Compounds onto Activated Alkenes: Access to Heterofused Indolizines and Pyrroloazepines. European Journal of Organic Chemistry 2017, 2017, 2462–2468. doi:10.1002/ejoc.201700123
• Guyon, H.; Boussonnière, A.; Castanet, A.-S. Readily Accessible 1,2-Amino Ether Ligands for Enantioselective Intramolecular Carbolithiation. The Journal of organic chemistry 2017, 82, 4949–4957. doi:10.1021/acs.joc.7b00423
• Ahmed, M.; Naseer, M. M. Organolithium-mediated cyclization reactions: a practical way to access hetero- and carbocycles. New Journal of Chemistry 2017, 41, 7824–7835. doi:10.1039/c7nj01763d
• Gómez-SanJuan, A.; Arrasate, S.; González-Díaz, H.; Sotomayor, N.; Lete, E. Perturbation Theory Modeling of Intramolecular Carbolithiation Reactions. In Proceedings of MOL2NET, International Conference on Multidisciplinary Sciences, MDPI, 2015; a013. doi:10.3390/mol2net-1-a013
• Dawaigher, S.; Månsson, K.; Ascic, E.; Artacho, J.; Mårtensson, R.; Loganathan, N.; Wendt, O. F.; Harmata, M.; Snieckus, V.; Wärnmark, K. A Protocol for the exo-Mono and exo,exo-Bis Functionalization of the Diazocine Ring of Tröger’s Base. The Journal of organic chemistry 2015, 80, 12006–12014. doi:10.1021/acs.joc.5b01921
• Mattalia, J.-M.; Nava, P. A Computational Study of the Intramolec­ular Carbolithiation of Aryllithiums: Solvent and Substituent Effects. European Journal of Organic Chemistry 2015, 2016, 394–401. doi:10.1002/ejoc.201501208
• Doulcet, J.; Stephenson, G. R. The Use of (−)‐Sparteine/Organolithium Reagents for the Enantioselective Lithiation of 7,8‐Dipropyltetrathia[7]helicene: Single and Double Kinetic Resolution Procedures. Chemistry (Weinheim an der Bergstrasse, Germany) 2015, 21, 18677–18689. doi:10.1002/chem.201502958

Explore citations to this article at