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Beilstein J. Org. Chem. 2024, 20, 2644–2654, doi:10.3762/bjoc.20.222
Graphical Abstract
Figure 1: Total ion chromatogram of an extract of the scent gland of a Mangshan pit viper. Compounds A–F are ...
Figure 2: Mass spectra of compounds A–F show characteristic similarities with m/z 141 and ions of the series m...
Figure 3: Structural proposals for compounds A–F.
Scheme 1: Synthesis of methyl 4,6-dimethyldodec-5-enoate (6). ACN: acetonitrile.
Figure 4: Mass spectrum of synthetic methyl (E)-4,6-dimethyldodec-5-enoate (E-6), identical with compound D.
Figure 5: Mass spectrum of cyclo(valyl-proline).