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1 article(s) from Liu, Tinglan

Recent advancements in iodide/phosphine-mediated photoredox radical reactions

Tinglan Liu,
Yu Zhou,
Junhong Tang and
Chengming Wang

Beilstein J. Org. Chem. 2023, 19, 1785–1803, doi:10.3762/bjoc.19.131

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Graphical Abstract

Scheme 1: Photocatalytic decarboxylative transformations mediated by the NaI/PPh₃ catalyst system.

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Scheme 2: Proposed catalytic cycle of NaI/PPh₃ photoredox catalysis.

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Scheme 3: Decarboxylative alkenylation of redox-active esters by NaI/PPh₃ catalysis.

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Scheme 4: Decarboxylative alkenylation mediated by NaI/PPh₃ catalysis.

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Scheme 5: NaI-mediated photoinduced α-alkenylation of Katritzky salts 7.

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Scheme 6: n-Bu₄NI-mediated photoinduced decarboxylative olefination.

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Scheme 7: Proposed mechanism of the n-Bu₄NI-mediated photoinduced decarboxylative olefination.

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Scheme 8: Photodecarboxylative alkylation of redox-active esters with diazirines.

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Scheme 9: Photoinduced iodine-anion-catalyzed decarboxylative/deaminative C–H alkylation of enamides.

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Scheme 10: Photocatalytic C–H alkylation of coumarins mediated by NaI/PPh₃ catalysis.

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Scheme 11: Photoredox alkylation of aldimines by NaI/PPh₃ catalysis.

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Scheme 12: Photoredox C–H alkylation employing ammonium iodide.

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Scheme 13: NaI/PPh₃/CuBr cooperative catalysis for photocatalytic C(sp³)–O/N cross-coupling reactions.

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Scheme 14: Proposed mechanism of NaI/PPh₃/CuBr cooperative catalysis for photocatalytic C(sp³)–O/N cross-coupl...

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Scheme 15: Photocatalytic decarboxylative [3 + 2]/[4 + 2] annulation between enynals and γ,σ-unsaturated N-(ac...

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Scheme 16: Proposed mechanism for the decarboxylative [3 + 2]/[4 + 2] annulation.

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Scheme 17: Decarboxylative cascade annulation of alkenes/1,6-enynes with N-hydroxyphthalimide esters.

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Scheme 18: Decarboxylative radical cascade cyclization of N-arylacrylamides.

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Scheme 19: NaI/PPh₃-driven photocatalytic decarboxylative radical cascade alkylarylation.

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Scheme 20: Proposed mechanism of the NaI/PPh₃-driven photocatalytic decarboxylative radical cascade cyclizatio...

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Scheme 21: Visible-light-promoted decarboxylative cyclization of vinylcycloalkanes.

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Scheme 22: NaI/PPh₃-mediated photochemical reduction and amination of nitroarenes.

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Scheme 23: PPh₃-catalyzed alkylative iododecarboxylation with LiI.

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Scheme 24: Visible-light-triggered iodination facilitated by N-heterocyclic carbenes.

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Scheme 25: Visible-light-induced photolysis of phosphonium iodide salts for monofluoromethylation.

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Review

Published 22 Nov 2023

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