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Beilstein J. Org. Chem. 2024, 20, 1053–1068, doi:10.3762/bjoc.20.93
Graphical Abstract
Figure 1: (a) Previously studied BBD-based photoswitches, (b) recently reported protocol to synthesize a BBD ...
Figure 2: Energy storage capacities and barrier for back conversion of the photoproduct to the diene in the g...
Figure 3: (a) Optimized geometry along with the important geometrical parameters of the TS obtained for the t...
Figure 4: Photophysical properties of the studied BBD photoswitches with elongated unsaturated bridges. (a) O...
Figure 5: Effect of solvation on the thermochemical properties of the studied BBD photoswitches considering t...
Figure 6: Effect of solvation on the photophysical properties of the studied BBD photoswitches. (a) Optical s...
Figure 7: The undesired degradation competing the thermal back conversion of the photoproduct. (a) The therma...
Figure 8: Relative energy profiles for the conversion of the photoproducts into the parent dienes and undesir...