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1 article(s) from Schmitz, Matthias

Mechanistic investigations of polyaza[7]helicene in photoredox and energy transfer catalysis

Johannes Rocker,
Till J. B. Zähringer,
Matthias Schmitz,
Till Opatz and
Christoph Kerzig

Beilstein J. Org. Chem. 2024, 20, 1236–1245, doi:10.3762/bjoc.20.106

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Scheme 1: Left: Reaction mechanism of the 3-CR with Aza-H as the photocatalyst. Potentials are given vs SCE. ...

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Figure 1: A) Room-temperature absorption (black) and emission (yellow) spectra of Aza-H recorded in MeCN/H₂O ...

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Figure 2: Mechanistic LFP experiments of 25 µM Aza-H with 4CP in MeCN/H₂O (9:1) after 355 nm laser pulses. A)...

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Figure 3: Mechanistic investigations of Aza-H with TsNa by LFP studies. A) Transient absorption measurements ...

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Figure 4: Data sets employed for the calculation Φ_ISC of Aza-H based on the ground state bleach of Rubpy as t...

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Figure 5: Stilbene isomerization and additional energy transfer experiments. A) and B) Triplet quenching expe...

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Published 28 May 2024

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