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Beilstein J. Org. Chem. 2024, 20, 2401–2407, doi:10.3762/bjoc.20.204
Graphical Abstract
Figure 1: Set of literature-known monocationic cyclic diaryliodonium(III) salts that were applied as XB donor...
Scheme 1: Synthesis of the iodoloisoxazolium salts 7Z: (a) 1.5 equiv 9, 0.2 equiv CuI, 2.0 equiv K2CO3, (THF)...
Figure 2: Halogen bonding dimer found in the crystal structure of 7Br. Ellipsoids are shown at 50% probabilit...
Scheme 2: Gold(I)-catalyzed cyclization of propargylic amide 11 as benchmark reaction for Au–Cl activation.
Figure 3: 1H NMR kinetics of the gold-catalyzed cyclization shown in Scheme 2. An equimolar amount of the gold comple...