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Beilstein J. Org. Chem. 2024, 20, 1428–1435, doi:10.3762/bjoc.20.125
Graphical Abstract
Scheme 1: Overview of halogen bonding.
Scheme 2: Correlation of orbital character on halogen with C–X–C bond angle for compounds 1–24; data from pri...
Scheme 3: Correlation of ΔG for XB bond formation and X---Cl distance for compounds 9–24 (green dots), 41–48 ...
Scheme 4: Correlation of X---Cl distance with van der Waals radii of X.
Scheme 5: Comparison of E(r) for XB complexes 9–12, 42–44, and 53–56.
Scheme 6: Correlation of p-character and Vs,max on X of XB donor with ΔG of XB bond.
Scheme 7: Model for ΔG based on Equation 1.
Beilstein J. Org. Chem. 2018, 14, 1034–1038, doi:10.3762/bjoc.14.90
Scheme 1: Imides as an important scaffold.
Scheme 2: Scope of compatible aryl groups. Conditions: 1 (0.5 mmol, 1 equiv), potassium phthalimide (2.5 mmol...
Scheme 3: One-pot synthesis of anilines.