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Beilstein J. Org. Chem. 2024, 20, 959–972, doi:10.3762/bjoc.20.86
Graphical Abstract
Figure 1: Biosynthetic pathway of terpenoids. Valuable terpenoids, noncanonical C11 and C16 terpenes are show...
Figure 2: Representative terpenoids produced by plant MSTSs. a) 6 and 7 are products of PamTps1 from Plectran...
Figure 3: The structure of representative terpene products of MSTSs. a) From fungi: compounds 30–33 are produ...
Figure 4: Terpenoid products of TSs using chemically synthesized noncanonical prenyl substrates. a) Products ...
Figure 5: Biotransformation of noncanonical prenyl analogs 60–65 using two terpene synthases, limonene syntha...
Figure 6: Noncanonical substrates for mechanism studies and their conversion to new terpenoids. a) New terpen...
Figure 7: A series of prenyl diphosphate building blocks produced by different IPP methyltransferases. humMT ...
Figure 8: The structure of noncanonical prenyl substrates generated by C-methyltransferases and variants. a) ...
Figure 9: Structures of C16 terpenes identified via genome mining of C16 biosynthetic gene clusters from bact...
Figure 10: a) Precursors and final products of the MVA pathway and LMVA pathway. b) The structure of C6- and C7...