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1 article(s) from Tarannam, Naziha

Stability trends in carbocation intermediates stemming from germacrene A and hedycaryol

Naziha Tarannam,
Prashant Kumar Gupta,
Shani Zev and
Dan Thomas Major

Beilstein J. Org. Chem. 2024, 20, 1189–1197, doi:10.3762/bjoc.20.101

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Scheme 1: Biosynthesis of (A) germacrene A and (B) hedycaryol from FPP. Here the abbreviations represent, FPP...

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Figure 1: 6-6 and 5-7 bicyclic carbocations formed by protonation and cyclization of germacrene A and hedycar...

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Figure 2: Bar plot for the relative free energies of germacrene A and hedycaryol carbocations relative to car...

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Figure 3: NCI plot for A (left) and B (right). Blue corresponds to repulsive and yellow represents slightly a...

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Figure 4: NCI plots for F and H hedycaryol cations. The C⁺···OH distances (Å) are shown in black.

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Figure 5: Correlation plot relating between the stability of hedycaryols (ΔΔE_e) and C⁺···OH bond distances.

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Published 23 May 2024

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