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Beilstein J. Org. Chem. 2019, 15, 1416–1424, doi:10.3762/bjoc.15.141
Graphical Abstract
Scheme 1: Stereospecific formation of α-enynes from alkynyloxiranes.
Scheme 2: Trapping experiments of the oxiranyllithium derived from cis or trans-alkynyloxiranes 1b, and their...
Scheme 3: Proposed mechanism for the rearrangement of alkynyloxiranes to α-enynes through metalation and bory...
Beilstein J. Org. Chem. 2013, 9, 1774–1780, doi:10.3762/bjoc.9.206
Scheme 1: Gold(I) or gold(III)-catalyzed furan syntheses with or without nucleophiles.
Scheme 2: Copper(I)-catalyzed 1,2-migration/cycloisomerization of γ-acyloxyalkynyl ketones.
Scheme 3: Mechanistic hypothesis for gold(I)-catalyzed conversion of γ-acyloxyalkynyl ketones into furans.