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1 article(s) from Yan, Jiajun

Radical chemistry in polymer science: an overview and recent advances

Zixiao Wang,
Feichen Cui,
Yang Sui and
Jiajun Yan

Beilstein J. Org. Chem. 2023, 19, 1580–1603, doi:10.3762/bjoc.19.116

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Graphical Abstract

Scheme 1: Oxidation of catechol and subsequent cross-linking. Scheme 1 redrawn from [3].

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Scheme 2: (A) Structure of typical urushiol in Chinese lacquer, and (B) schematic process of laccase-catalyze...

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Scheme 3: A) Primary amino acid sequence of mfp-1, mfp-3, and mfp-5 (Y: DOPA, K: lysine). B) Scheme showing e...

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Scheme 4: Activation–deactivation equilibrium in nitroxide-mediated polymerizations. Bicomponent initiating s...

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Scheme 5: Mechanism of a transition metal complex-mediated ATRP. Scheme 5 redrawn from [14].

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Scheme 6: Mechanism of RAFT polymerization. Scheme 6 redrawn from [68].

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Scheme 7: Degenerative transfer (a) and reversible termination (b) mechanism of OMRP. Scheme 7 redrawn from [70].

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Scheme 8: Simplified mechanism of a RITP. Scheme 8 redrawn from [21].

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Scheme 9: (A) Structures of π-conjugated conductive polymers. (B) Examples of conductive polymer synthesis vi...

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Scheme 10: Possible regiochemical couplings in PATs. Scheme 10 redrawn from [79].

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Scheme 11: General thiol-ene photopolymerization process. Scheme 11 redrawn from [81].

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Scheme 12: (a) Three generations of Grubbs catalysts. (b) Proposed mechanism for photo-ROMP via a reductive qu...

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Scheme 13: Pyrylium and thiopyrylium salts studied by Boydston et al. Scheme 13 redrawn from [91].

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Scheme 14: A general illustration of post-polymerization modification by thiol–ene chemistry.

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Scheme 15: Introduction of functionalities by nitroxide radical coupling of HO-TEMPO derivatives.

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Scheme 16: Chemical reaction process scheme of DCP-induced crosslinking of LDPE. Scheme 16 redrawn from [126].

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Scheme 17: A probable mechanism of radical-induced hydrosilylation.

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Scheme 18: Polymer surface modification by homolytic dediazonation of diazonium salts.

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Scheme 19: Photoinduced polymer surface modification or surface grafting using benzophenone.

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Scheme 20: Depolymerization mechanism of common photoresists. (a) A possible mechanism of radiation decomposit...

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Scheme 21: Proposed mechanisms of photooxidative depolymerization of polystyrene. (a) Scheme 21a was reprinted with perm...

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Review

Published 18 Oct 2023

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