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Beilstein J. Org. Chem. 2024, 20, 1785–1793, doi:10.3762/bjoc.20.157
Graphical Abstract
Scheme 1: Examples of fluorination using hypervalent iodine(III) reagents 1 and 2.
Scheme 2: Preparations and reactions of hypervalent iodine(V) fluorides.
Figure 1: Bicyclic difluoro(aryl)-λ5-iodanes.
Scheme 3: Attempted oxidative fluorination of hypervalent iodine(III) amides.
Scheme 4: Synthesis of methyl(trifluoromethyl)fluoroiodane 15.
Scheme 5: Synthesis of bis(trifluoromethyl)fluoroiodane 19.
Scheme 6: Reaction of phenylmagnesium bromide with bis(trifluoromethyl)trifluoroiodane 22.
Figure 2: Molecular structure of difluoroiodane 6 showing 50% displacement ellipsoids.
Figure 3: Stability of difluoroiodane 6 in air in dry CD3CN (blue line), dry CDCl3 with 2.4 equivalents of dr...
Figure 4: Order of hydrolytic stability for the four hypervalent iodine(V) fluorides.
Beilstein J. Org. Chem. 2017, 13, 1039–1049, doi:10.3762/bjoc.13.103
Figure 1: Structures of 1–6 and 2a–4a.
Figure 2: Representatives of the theoretical dominant conformers of (4R,6R,αS)-1 ((S)-1a1 and (S)-1b1) and (4R...
Figure 3: Comparison of the experimental ECD spectrum of 1 with the M11/TZVP calculated spectra of (4R,6R,αS)-...
Figure 4: Comparison of the experimental ECD spectrum with the BH&HLYP/TZVP calculated spectra of the mixture...
Figure 5: UPLC analysis of photoreaction products of 2 (around tR = 7.5 min) and 3 (around tR = 11.5 min).
Figure 6: Potential energy surfaces of 2a/3a in the S0, S1, and T1 states, geometries of key points in the su...
Beilstein J. Org. Chem. 2016, 12, 2682–2688, doi:10.3762/bjoc.12.265
Scheme 1: Previous and present EDOT functionalization routes.
Scheme 2: The synthetic route from glycidol to pyEDOT (3).
Scheme 3: The synthetic route from D-mannitol diketal to eEDOT 8 and TMS-eEDOT 8’.
Scheme 4: New EDOT derivatives 9–13 accessible from pyEDOT with bromo-pendant group precursors via Sonogashir...
Figure 1: CVs of electrochemical polymerization of (a) pyEDOT 3 and (b) EDOT in MeCN solution with 0.1 M TEAPF...
Figure 2: CVs of electrochemical polymerization of (a) pyEDOT-DeT (9), (b) pyEDOT-AQ (12) and (c) pyEDOT-MVPF...