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1 article(s) from Yang, Zhiyao

Hydrogen-bonded macrocycle-mediated dimerization for orthogonal supramolecular polymerization

Wentao Yu,
Zhiyao Yang,
Chengkan Yu,
Xiaowei Li and
Lihua Yuan

Beilstein J. Org. Chem. 2025, 21, 179–188, doi:10.3762/bjoc.21.10

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Graphical Abstract

Scheme 1: a) Chemical structures of H-bonded macrocycles H1, H2, and guest G1, and schematic representation o...

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Figure 1: ESIMS spectrum of an equimolar mixture of G1 and H1 in CHCl₃/CH₃CN (1:1, v/v), including calculated...

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Figure 2: Stacked ¹H NMR spectra (CDCl₃/CD₃CN 1:1, v/v, 400 MHz, 298 K) of G1 upon addition of different equi...

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Figure 3: Single-crystal X-ray structure of the complex H2 ⊃ G1. a) Dimeric structure formed by cyclo[6]arami...

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Figure 4: Stacked ¹H NMR spectra (CDCl₃/CD₃CN 1:1, v/v, 400 MHz, 298 K) of G2 upon addition of different equi...

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Figure 5: TEM images of a solution of H1, G2, and Zn(ClO₄)₂ at different concentrations (CHCl₃/CH₃CN 1:1, v/v...

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Figure 6: Stacked ¹H NMR spectra (CDCl₃/CD₃CN 1:1, v/v, 400 MHz, 298 K) of G2 and Zn²⁺ upon addition of diffe...

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Figure 7: Specific viscosity of the linear supramolecular polymer in CHCl₃/CH₃CN (1:1, v/v, 298 K) at variabl...

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Figure 8: Variable-concentration ¹H NMR spectra of the supramolecular polymer: (a) 2.0 mM, (b) 4.0 mM, (c) 6....

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Published 17 Jan 2025

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