Beilstein J. Org. Chem.2009,5, No. 54, doi:10.3762/bjoc.5.54
ligand extensively used in the synthesis of cyclometallated iridium(III) and platinum(II) derivatives [46][47] but whose reactivity towards Pd(II) centres is unexplored. This kind of ligand has been functionalised with a chiral group such as a cholesteryl ester unit, introduced as terminal substituent in
soft materials with non-conventional structures.
Platinum(II) and Zinc(II)
For the less explored Pt(II) and Zn(II) metal centres versatile 2,2′-bipyridines have been selected since they are well-known building blocks for the formation of inorganic functional nanomaterials [51]. The complexation of non
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Graphical Abstract
Figure 1:
Molecular structure of NIRPAC: a Pd(II) complex based on Nile red and a curcumin derivative.