Beilstein J. Org. Chem.2006,2, No. 4, doi:10.1186/1860-5397-2-4
phosphorchloridate with thiols [22][23][24][25][26] and (iii) redox-type reactions of phosphorus triesters with thiols in the presence of tellurium (IV) chloride. [27][28] However, all of these methods have problems, including drastic reaction conditions and also some severe side reactions. Surface-mediated solid
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Graphical Abstract
Scheme 1:
Synthesis of phosphorothioates using microwave irradiation