Beilstein J. Org. Chem.2012,8, 597–605, doi:10.3762/bjoc.8.66
can be reverted as needed (active–latent strategy). Direct conjugation of the AP moiety to biomolecules, monolayers, arrays, etc., should be possible by executing thiol–ene chemistry [43], ozonolysis/reductive amination [44][45][46], or other ligation protocols [47][48].
Experimental
General remarks
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Graphical Abstract
Scheme 1:
Orthogonal strategy introduced by Ogawa et al.
Beilstein J. Org. Chem.2010,6, 1132–1148, doi:10.3762/bjoc.6.130
via the thiol–ene chemistry [47].
Controlled radical polymerizations
Controlled radical polymerization techniques are suitable for synthesizing polymers with a high level of architectural control. They not only allow the copolymerization with functional monomers as discussed previously for free
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Graphical Abstract
Figure 1:
Copolymerization of 2 monomers A and B with different polarities in direct miniemlusions with the d...