Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

• Toshiki Nokami,
• Ryoji Soma,
• Yoshimasa Yamamoto,
• Toshiyuki Kamei,
• Kenichiro Itami and
• Jun-ichi Yoshida

Beilstein J. Org. Chem. 2007, 3, No. 7, doi:10.1186/1860-5397-3-7

• " method, which involves the irreversible oxidative generation and accumulation of highly reactive cations in the absence of nucleophiles [1][2][3][4][5]. Heteroatom-stabilized carbocations, such as N-acyliminium ion pools and alkoxycarbenium ion pools have been generated based on oxidative C-H, C-Si, and

• organosilicon cation 3d and silyl radical 4d by DFT calculations (B3LYP/LANL2DZ). Electrochemical generation of carbocations by oxidative C-C bond dissociation. Electrochemical generation and accumulation of organosilicon cation by oxidative Si-Si bond dissociation. Electrochemical generation of organosilicon