Conformational rigidity of silicon- stereogenic silanes in asymmetric catalysis: A comparative study

• Sebastian Rendler and
• Martin Oestreich

Beilstein J. Org. Chem. 2007, 3, No. 9, doi:10.1186/1860-5397-3-9

• based on silicon-stereogenic reagents or substrates were revisited or invented. [1][2][3][4] Aside from the use of silicon-stereogenic chiral auxiliaries in substrate-controlled reactions, [5] a still limited number of remarkable stereoselective processes with a stereogenic silicon as the reactive site